{"id":"W4390646398","doi":"10.1016/j.cej.2024.148631","title":"UVA LED-assisted breakdown of persulfate oxidants for the treatment of real oil sands process water: Removal of naphthenic acids and evaluation of residual toxicity","year":2024,"lang":"en","type":"article","venue":"Chemical Engineering Journal","topic":"Petroleum Processing and Analysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Canada First Research Excellence Fund; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior; Alberta Innovates; Imperial Oil Resources; EPCOR; Fundação de Amparo à Pesquisa do Estado de São Paulo; Teck Resources; Canadian Natural Resources Limited; University of Alberta; Canada's Oil Sands Innovation Alliance; Syncrude; Conselho Nacional de Desenvolvimento Científico e Tecnológico; Alberta Environment and Parks; Suncor Energy Incorporated","keywords":"Persulfate; Chemistry; Human decontamination; Toxicity; Environmental chemistry; Bioassay; Naphthenic acid; Environmental remediation; Contamination; Pulp and paper industry; Waste management; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000489643,0.000143211,0.0003599787,0.00008242913,0.00003060922,0.00001662108,0.0001326169,0.00009870424,0.00002823144],"category_scores_gemma":[0.0001027243,0.00008645746,0.0001934853,0.0001250639,0.00007941695,0.00005664621,0.0000139176,0.0001221631,4.849453e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000838093,"about_ca_system_score_gemma":0.0001018237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009423386,"about_ca_topic_score_gemma":2.998682e-7,"domain_scores_codex":[0.9987845,0.00001097395,0.0004896564,0.0001472057,0.0004043361,0.0001632723],"domain_scores_gemma":[0.9992598,0.0001267886,0.000150576,0.0001327016,0.0002739949,0.00005618245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001247374,0.0001027809,0.00006173262,0.001096883,0.0004260912,0.000002478217,0.0008454989,0.002073241,0.9477341,0.000003237862,0.000002801119,0.04752645],"study_design_scores_gemma":[0.0009708075,0.00006596572,0.0001004746,0.0005269239,0.0007224777,0.0001399887,0.0001330467,0.06500179,0.9322018,0.00002580645,0.00003013622,0.00008075952],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954449,0.003930636,0.0002871313,0.00005028572,0.00003289011,0.00001056496,0.00002903411,0.00001486313,0.0001996971],"genre_scores_gemma":[0.9987429,0.0003983168,0.0005826482,4.50927e-7,0.000111248,0.000005707487,0.000009363534,0.00001693439,0.0001324165],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06292855,"threshold_uncertainty_score":0.3525633,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0178861980052146,"score_gpt":0.2782664585929255,"score_spread":0.2603802605877109,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}