{"id":"W4390655963","doi":"10.1002/ange.202318829","title":"Guest‐Shuttling in a Nanosized Metallobox","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"Ministerio de Ciencia e Innovación; Universitat Jaume I; Conselleria de Cultura, Educación y Ciencia, Generalitat Valenciana; Generalitat Valenciana","keywords":"Janus; Planar; Molecule; Ligand (biochemistry); Affinities; Chemistry; Iridium; Pyrazine; Nanotechnology; Chemical physics; Crystallography; Materials science; Stereochemistry; Computer science; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001186574,0.0002231527,0.0002356426,0.00004983231,0.00004134226,0.0001190231,0.0002534516,0.0001594333,0.001742616],"category_scores_gemma":[0.00007212941,0.0002190002,0.000171867,0.0002805458,0.00005365194,0.0001172589,0.00008653741,0.0003101638,0.0000937032],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008278464,"about_ca_system_score_gemma":0.00006499522,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003657925,"about_ca_topic_score_gemma":0.000009356562,"domain_scores_codex":[0.9987429,0.000007211903,0.0002574423,0.0004417768,0.000203053,0.0003476589],"domain_scores_gemma":[0.9994285,0.00009870059,0.0000271618,0.000337244,0.00001916889,0.00008919277],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001818148,0.00004115675,0.0001749863,0.0003153269,0.00006112046,0.0003360058,0.0001856523,0.000002283046,0.9968913,0.0001474474,0.001436185,0.0003903591],"study_design_scores_gemma":[0.0003232189,0.000003493337,0.000005130362,0.0002343534,0.00003400184,0.00005018168,0.0001101661,0.00005784871,0.9015191,0.00059787,0.09682432,0.0002402978],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8284128,0.008764027,0.000025175,0.0002959385,0.0002886604,0.00005017806,0.00002139075,0.0004627252,0.1616791],"genre_scores_gemma":[0.9943615,0.0001096938,0.0002111615,0.0001027517,0.0005007209,0.00005293906,0.00008152969,0.0000428458,0.004536901],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1659486,"threshold_uncertainty_score":0.9991699,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01794818973116477,"score_gpt":0.2548848762900535,"score_spread":0.2369366865588887,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}