{"id":"W4390661799","doi":"10.1002/ejoc.202301205","title":"C‐Centered radical intermediates for C(sp<sup>3</sup>)‐H bonds functionalization: An emerging approach towards alkyl thiocyanates","year":2024,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Institut Carnot Santé Animale; Canada Foundation for Innovation; Université de Rouen; Région Normandie; Université de Montréal; Centre National de la Recherche Scientifique; Agence Nationale de la Recherche; Natural Sciences and Engineering Research Council of Canada; European Regional Development Fund; Centre in Green Chemistry and Catalysis; European Commission; Indian National Science Academy","keywords":"Chemistry; Surface modification; Moiety; Combinatorial chemistry; Alkyl; Thiocyanate; Molecule; Organic synthesis; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002740716,0.0006111896,0.0002818502,0.0002563494,0.0001718246,0.000277568,0.0002937938,0.0005621939,0.002018531],"category_scores_gemma":[0.0001088462,0.0001448933,0.000320076,0.0002044946,0.0003079426,0.0004597067,0.0003479042,0.0006428555,0.0007051028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002489119,"about_ca_system_score_gemma":0.0002407431,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002292056,"about_ca_topic_score_gemma":0.0004434128,"domain_scores_codex":[0.9999124,0.00001746765,0.000005637467,0.00001690354,0.0000232066,0.00002438338],"domain_scores_gemma":[0.9999515,0.0000140203,0.00001367777,0.00000366013,0.0000102528,0.000006833446],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009446315,0.00009280477,0.00009624968,0.001393661,0.00003250256,0.000425942,0.0001438436,0.0008220045,0.9558451,0.007642228,0.000866712,0.03254465],"study_design_scores_gemma":[0.00005249502,0.00142823,0.0004331897,0.00007825346,0.00005781737,0.0007373307,0.00006922804,0.001555057,0.9393284,0.001344925,0.05487993,0.00003519237],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6356583,0.2022343,0.1101637,0.001894568,0.0009822004,0.0004595094,0.000345283,0.0008331082,0.04742903],"genre_scores_gemma":[0.8557302,0.1079271,0.02517687,0.0004913805,0.0002751472,0.0001752682,0.0002107395,0.00007003207,0.009943459],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002018531,"threshold_uncertainty_score":0.00675267,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02417886905937092,"score_gpt":0.2594807729188093,"score_spread":0.2353019038594384,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}