{"id":"W4390812808","doi":"10.1055/s-0043-1763656","title":"Nickel-Catalyzed Synthesis of Benzylamines from (Hetero)aryl Halides and Glycine-Derived N-Hydroxyphthalimide Esters","year":2024,"lang":"en","type":"article","venue":"Synlett","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"University of Toronto","keywords":"Chemistry; Aryl; Catalysis; Reagent; Nickel; Halide; Glycine; Carbamate; Electrophile; Organic chemistry; Combinatorial chemistry; Amino acid; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001896252,0.0004740883,0.0002546194,0.0001520355,0.0001575462,0.0001741655,0.0005191742,0.0002268034,0.002875512],"category_scores_gemma":[0.0002179823,0.0001707625,0.0001691404,0.0001736938,0.0001367897,0.0003153223,0.0003144479,0.0004517535,0.002429929],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002743398,"about_ca_system_score_gemma":0.00041228,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005723166,"about_ca_topic_score_gemma":0.00197757,"domain_scores_codex":[0.9998683,0.0000128883,0.00001567701,0.00002492343,0.00004404156,0.0000341724],"domain_scores_gemma":[0.999923,0.000007801793,0.00001527261,0.00001513045,0.00001735207,0.00002135787],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008344424,0.00003194847,0.00008549845,0.0002937139,0.00001549061,0.0003876541,0.00008118387,0.0002284603,0.9890811,0.0008026974,0.0004840884,0.008424746],"study_design_scores_gemma":[0.00001966231,0.0001357288,0.0003619281,0.00001572917,0.00001234123,0.0002960854,0.0000151411,0.0002729624,0.9888797,0.00007600274,0.009906182,0.000008500826],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8226496,0.006247585,0.08450644,0.0004489691,0.0003420997,0.0007513657,0.004074636,0.001480429,0.07949885],"genre_scores_gemma":[0.955354,0.005084287,0.02273034,0.0000910267,0.00003859234,0.0001791593,0.001490707,0.0001830123,0.01484885],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002875512,"threshold_uncertainty_score":0.009619534,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01852950495373539,"score_gpt":0.2662945911104418,"score_spread":0.2477650861567064,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}