{"id":"W4390838949","doi":"10.1093/ce/zkad071","title":"The relationship between oxidative degradation and ammonia emission of carbon capture amines based on their chemical structures","year":2024,"lang":"en","type":"article","venue":"Clean Energy","topic":"Carbon Dioxide Capture Technologies","field":"Engineering","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"Natural Sciences and Engineering Research Council of Canada; SaskPower","keywords":"Chemistry; Amine gas treating; Alkyl; Tertiary amine; Steric effects; Degradation (telecommunications); Ammonia; Primary (astronomy); Radical; Chemical structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002157718,0.0003006123,0.0001771431,0.000156078,0.0001022483,0.0001965434,0.0001428557,0.0003200358,0.0007281927],"category_scores_gemma":[0.000444267,0.0001423272,0.0002350363,0.0001319811,0.0001955587,0.0002631038,0.0001247909,0.0003193881,0.000156096],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001683446,"about_ca_system_score_gemma":0.0001049204,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006220114,"about_ca_topic_score_gemma":0.001547328,"domain_scores_codex":[0.9997893,0.00002443424,0.00001430346,0.0000437773,0.00008288163,0.00004542505],"domain_scores_gemma":[0.9995245,0.0001460961,0.0001248678,0.00001659074,0.000151069,0.00003693792],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001011978,0.00001186522,0.0006243247,0.00005288392,0.00001148467,0.00002331332,0.00001576682,0.0001201909,0.9978156,0.00001144508,0.000008988684,0.001202799],"study_design_scores_gemma":[0.000001956726,0.0002800048,0.008097269,0.000004565117,0.00001493477,0.00002882754,0.00002723536,0.0006467207,0.9906347,0.000007360096,0.0002517866,0.000004560405],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979317,0.0006649613,0.0007037545,0.00001366432,0.00001169612,0.00001100532,0.00008266005,0.000008584861,0.0005719432],"genre_scores_gemma":[0.997736,0.0004651903,0.0008571157,0.00001959367,0.000005130261,0.00001799924,0.0001163369,0.000006360623,0.0007763374],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007281927,"threshold_uncertainty_score":0.002436042,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01471160031770111,"score_gpt":0.2187029452038756,"score_spread":0.2039913448861745,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}