{"id":"W4391027527","doi":"10.1002/cctc.202301290","title":"Mimicking Non‐Canonical Radical Cyclizations in the Synthesis of Dibenzocyclooctadiene Natural Products","year":2024,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Plant-derived Lignans Synthesis and Bioactivity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Radical; Chemistry; Redox; Oxidative phosphorylation; Combinatorial chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002404019,0.0001989415,0.00009482561,0.0001114569,0.00009760104,0.0002751516,0.0002001924,0.0001849446,0.001308158],"category_scores_gemma":[0.0001465679,0.00008848507,0.0001289126,0.0001013806,0.0001947751,0.0002927445,0.0001822145,0.0003500332,0.0003008254],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002428841,"about_ca_system_score_gemma":0.0002099321,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002389683,"about_ca_topic_score_gemma":0.0006696625,"domain_scores_codex":[0.9999303,0.00001295153,0.000005121006,0.00001677393,0.00001680852,0.00001802235],"domain_scores_gemma":[0.9999259,0.00001812956,0.00002123494,0.00001254038,0.00001171314,0.00001057969],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004601919,0.00005765261,0.0001429285,0.00005957149,0.000004956548,0.00008650457,0.00003727113,0.0004949648,0.9916456,0.00310826,0.00005885579,0.004257398],"study_design_scores_gemma":[0.000009986133,0.0002609061,0.0003013985,0.000003417753,0.000005277112,0.0001027119,0.00001761606,0.0009812298,0.993242,0.0003658764,0.004703951,0.000005687762],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9577142,0.001632494,0.03018584,0.0002714572,0.00009739431,0.00008458876,0.0001184635,0.0001522376,0.009743306],"genre_scores_gemma":[0.9829707,0.001190118,0.01253593,0.00006229786,0.00001122193,0.00002469961,0.0000913542,0.00002806471,0.003085627],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001308158,"threshold_uncertainty_score":0.004376292,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009447261138686661,"score_gpt":0.2382680384934701,"score_spread":0.2288207773547835,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}