{"id":"W4391092140","doi":"10.1021/acs.chemmater.3c02288","title":"Enantiopure Chiral Au<sub>13</sub> Nanoclusters Stabilized by Ditopic <i>N</i>-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO<sub>2</sub>","year":2024,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Social Sciences and Humanities Research Council of Canada; Natural Sciences and Engineering Research Council of Canada; Research Foundation for the Electrotechnology of Chubu; American Chemical Society Petroleum Research Fund; Japan Society for the Promotion of Science; Ministry of Education, Culture, Sports, Science and Technology; Canada Foundation for Innovation","keywords":"Nanoclusters; Chemistry; Enantiopure drug; Enantiomer; Chirality (physics); Circular dichroism; Crystallography; Electrospray ionization; Density functional theory; Superatom; Mass spectrometry; Stereochemistry; Computational chemistry; Enantioselective synthesis; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005720297,0.0001651601,0.0001925393,0.0001003889,0.0001322488,0.0002487957,0.0002433377,0.0001900038,0.0004546032],"category_scores_gemma":[0.000176948,0.0001187147,0.00007547134,0.00009936731,0.0002452313,0.0001054908,0.000163106,0.0002257529,0.0001753097],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004947065,"about_ca_system_score_gemma":0.0002002279,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001492352,"about_ca_topic_score_gemma":0.003500141,"domain_scores_codex":[0.9999219,0.000005055162,0.000005479545,0.00002183346,0.00003090419,0.00001489009],"domain_scores_gemma":[0.9999188,0.000009221416,0.00002585115,0.00001025091,0.00001870867,0.00001712575],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004506869,0.000009734627,0.0002036125,0.00001629384,0.000003333553,0.00002394,0.00001000317,0.0003398012,0.997858,0.0001262874,0.00003771891,0.001326129],"study_design_scores_gemma":[0.000002749523,0.00003177836,0.0006767911,8.28143e-7,0.000004010736,0.00003611642,0.000007188025,0.001417254,0.9974588,0.00001653239,0.0003457276,0.000002199566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934109,0.0002499283,0.004134384,0.0000361574,0.00001069079,0.00002842735,0.0001298862,0.0001237197,0.001875822],"genre_scores_gemma":[0.9930151,0.0001081567,0.00576679,0.00002399404,0.000001733038,0.00001382683,0.0001057742,0.00002092103,0.000943665],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001492352,"threshold_uncertainty_score":0.003589332,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006084504747363521,"score_gpt":0.2145821960984534,"score_spread":0.2084976913510899,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}