{"id":"W4391092140","doi":"10.1021/acs.chemmater.3c02288","title":"Enantiopure Chiral Au<sub>13</sub> Nanoclusters Stabilized by Ditopic <i>N</i>-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO<sub>2</sub>","year":2024,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Social Sciences and Humanities Research Council of Canada; Natural Sciences and Engineering Research Council of Canada; Research Foundation for the Electrotechnology of Chubu; American Chemical Society Petroleum Research Fund; Japan Society for the Promotion of Science; Ministry of Education, Culture, Sports, Science and Technology; Canada Foundation for Innovation","keywords":"Nanoclusters; Chemistry; Enantiopure drug; Enantiomer; Chirality (physics); Circular dichroism; Crystallography; Electrospray ionization; Density functional theory; Superatom; Mass spectrometry; Stereochemistry; Computational chemistry; Enantioselective synthesis; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004110792,0.000346372,0.0006662853,0.00006850545,0.000137482,0.0001662022,0.0003187179,0.0002175088,0.00009580039],"category_scores_gemma":[0.00009038869,0.0003232744,0.0001043458,0.0001913752,0.0003136328,0.0002985871,0.0000955741,0.00007566702,0.00001860874],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009604761,"about_ca_system_score_gemma":0.000117575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002025498,"about_ca_topic_score_gemma":0.000001506627,"domain_scores_codex":[0.9976249,0.00009319755,0.000909,0.000660309,0.0003140964,0.0003985402],"domain_scores_gemma":[0.9987307,0.0001179958,0.0004342246,0.0005108595,0.00009033417,0.0001158937],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006144708,0.00007944518,0.00001876489,0.001794184,0.00003753994,0.000001030794,0.000195288,0.000001209688,0.9964188,0.000010043,0.0003984716,0.0009837461],"study_design_scores_gemma":[0.0002356207,0.00002668985,0.0001498139,0.0004293625,0.0001226793,0.00003963019,0.00006319054,0.00001056168,0.9981462,0.00005984399,0.0004172852,0.0002990983],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972227,0.0003488568,0.0002061327,0.0002223937,0.0004559083,0.000386578,0.001002298,0.0001042663,0.00005085988],"genre_scores_gemma":[0.9985375,0.0004046985,0.00004314802,0.00001168579,0.0003168998,0.0001928115,0.0003582135,0.00005317669,0.00008186772],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001727394,"threshold_uncertainty_score":0.9999219,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006084504747363521,"score_gpt":0.2145821960984534,"score_spread":0.2084976913510899,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}