{"id":"W4391106344","doi":"10.1016/j.cej.2024.148981","title":"Stratification of polyisocyanate in two-component waterborne polyurethane films","year":2024,"lang":"en","type":"article","venue":"Chemical Engineering Journal","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; BASF Corporation; BASF","keywords":"Polyurethane; Materials science; Trimer; Chemical engineering; Hexamethylene diisocyanate; Polyol; Coating; Polyethylene glycol; Plasticizer; Polymer; Polymer chemistry; Nanotechnology; Composite material; Chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002737594,0.0001099697,0.0001709132,0.0001226689,0.00001766999,0.00009061536,0.0001758697,0.00004224694,0.0001283708],"category_scores_gemma":[0.00002101334,0.0000940195,0.00006337225,0.0001525833,0.00002090426,0.0001293496,0.00002808123,0.0002794685,0.00001319507],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006012501,"about_ca_system_score_gemma":0.00003313737,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003344287,"about_ca_topic_score_gemma":2.778508e-7,"domain_scores_codex":[0.9990183,0.00001314561,0.0003826832,0.0001476217,0.0001853318,0.0002529822],"domain_scores_gemma":[0.9996734,0.00005416569,0.00004337063,0.0001043674,0.00001964053,0.0001050199],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001047736,0.00002117101,0.00001496691,0.00006356085,0.000006756221,0.00002580855,0.000175665,0.008388221,0.9903879,0.0004289853,0.00002426496,0.0004521773],"study_design_scores_gemma":[0.0001673621,0.00001099922,0.00007642405,0.0002076788,0.000007546781,0.0001194813,0.000009707369,0.1171695,0.8819975,0.00009390494,0.00004607012,0.00009377226],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9828809,0.002571951,0.01358176,0.0002235452,0.0005727719,0.00003961082,0.000005984968,0.00006195908,0.0000615282],"genre_scores_gemma":[0.9908697,0.00002242825,0.00891207,0.00001029494,0.0001500395,0.000002156283,0.000004689786,0.00001589713,0.00001270252],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1087813,"threshold_uncertainty_score":0.3834004,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007776924982315955,"score_gpt":0.2379181095661322,"score_spread":0.2301411845838162,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}