{"id":"W4391142498","doi":"10.26434/chemrxiv-2024-fx65b","title":"Synthesis and reactivity of bis-tris(pyrazolyl)borate lanthanide-aluminium heterobimetallic trihydride complexes","year":2024,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Glasgow; University of Guelph","keywords":"Lanthanide; Aluminium; Boron; Tris; Reactivity (psychology); Chemistry; Inorganic chemistry; Nuclear chemistry; Organic chemistry; Biochemistry; Medicine","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004148723,0.0006446055,0.001218325,0.00008389219,0.00006903194,0.0001540508,0.0005018624,0.0007740086,0.001543512],"category_scores_gemma":[0.0003151355,0.000641567,0.0002986025,0.0001226213,0.0002915851,0.00005833424,0.001407658,0.000781457,0.00004312586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001016369,"about_ca_system_score_gemma":0.0002256031,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001600327,"about_ca_topic_score_gemma":0.00000716794,"domain_scores_codex":[0.9974571,0.00003539562,0.0007832017,0.001004571,0.0002890837,0.0004305982],"domain_scores_gemma":[0.9977616,0.0003612295,0.0005453312,0.001067497,0.0001050367,0.0001593227],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009009604,0.0001133213,0.00005006095,0.01017294,0.0003310182,0.00006908665,0.0001250387,0.000002538028,0.9878819,0.00007858135,0.0008075654,0.000277878],"study_design_scores_gemma":[0.0002379923,0.000007191835,0.00005329452,0.00105678,0.0005145578,0.00006631811,0.00006773246,0.00002299096,0.9935156,0.001498005,0.002368506,0.0005911043],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9849821,0.001077326,0.000003959054,0.0001489426,0.0004298685,0.0001389125,0.0004184236,0.0002509692,0.01254955],"genre_scores_gemma":[0.9964611,0.0007246102,0.0001293636,0.00001923986,0.0004180968,0.00009630567,0.0001635186,0.0001093928,0.001878377],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01147904,"threshold_uncertainty_score":0.9996036,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02259654238702522,"score_gpt":0.2502878975549202,"score_spread":0.227691355167895,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}