{"id":"W4391163870","doi":"10.1021/acsanm.3c04780","title":"Open Air Direct Oxidative Coupling of Alcohols and Amines to Imines Catalyzed by Ruthenium Nanoclusters Supported on a Mesoporous Carbon (CMK-8) in/on Water","year":2024,"lang":"en","type":"article","venue":"ACS Applied Nano Materials","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Institute for Advanced Studies in Basic Sciences; Iran National Science Foundation; Iran Science Elites Federation; Alexander von Humboldt-Stiftung","keywords":"Nanoclusters; Ruthenium; Catalysis; Mesoporous material; Oxidative coupling of methane; Coupling (piping); Carbon fibers; Chemistry; Photochemistry; Materials science; Chemical engineering; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004310445,0.0003359493,0.0006977713,0.0003431698,0.00005111689,0.0001537161,0.0003997464,0.0001723741,0.0002560533],"category_scores_gemma":[0.00003779609,0.000253043,0.00004016007,0.0004261107,0.00005359836,0.00008175753,0.0003273275,0.00006899659,0.0000394962],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009011946,"about_ca_system_score_gemma":0.00002582597,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004403176,"about_ca_topic_score_gemma":0.00001567918,"domain_scores_codex":[0.9980607,0.00001624289,0.0006167745,0.0006612508,0.0003028769,0.0003421578],"domain_scores_gemma":[0.9991816,0.0001461602,0.0001271152,0.0004001427,0.00004423006,0.000100764],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003181084,0.00008685699,0.0000184175,0.0001930637,0.0001477807,0.00001402964,0.001225538,0.00003561253,0.9970898,0.00007406287,0.0004374915,0.0003592267],"study_design_scores_gemma":[0.0007243455,0.0000352291,0.00001197564,0.0001136712,0.00008061175,0.000002587421,0.0004078731,0.00002164131,0.9972699,0.00003241384,0.0009884305,0.0003113088],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927178,0.00007901389,0.000001169695,0.0002089521,0.0001240855,0.0004950985,0.0003537295,0.00008481686,0.005935347],"genre_scores_gemma":[0.9975934,0.00003037974,0.00001802855,0.0001377713,0.00005524534,0.000301521,0.0007546368,0.00005778667,0.00105123],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004884118,"threshold_uncertainty_score":0.9999922,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01090942845510066,"score_gpt":0.2530584190741489,"score_spread":0.2421489906190483,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}