{"id":"W4391246482","doi":"10.1055/s-0042-1751550","title":"Synthesis of Heterodiarylmethanes via Metallaphotoredox Decarboxylative Arylation","year":2024,"lang":"en","type":"article","venue":"Synlett","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Paraza Pharma (Canada)","funders":"","keywords":"Chemistry; Combinatorial chemistry; Decarboxylation; Organic chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001211375,0.0001598243,0.0002442572,0.00009056735,0.0000306006,0.00002434039,0.0001599792,0.0001489135,0.001822991],"category_scores_gemma":[0.0004748782,0.0001428549,0.000207153,0.0002503282,0.0001345532,0.0001336499,0.00003647754,0.0002277644,0.0001110514],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008247353,"about_ca_system_score_gemma":0.00003542235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001263936,"about_ca_topic_score_gemma":0.000004674463,"domain_scores_codex":[0.99888,0.00002281975,0.0003076561,0.0003074597,0.0002897601,0.0001923244],"domain_scores_gemma":[0.9984233,0.001073042,0.00006447712,0.000298513,0.00004068784,0.0001000162],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001611058,0.00004035415,0.0000665072,0.0002020186,0.0001699071,0.00001391731,0.00007816847,0.000008469401,0.9915462,0.0003311881,0.000347487,0.007179631],"study_design_scores_gemma":[0.00005377715,0.000007072782,0.00007864129,0.0001449318,0.0001065431,0.00001369716,0.00001975947,0.002451464,0.9892183,0.003560992,0.004197521,0.000147309],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9350386,0.001049116,0.001243073,0.0003243625,0.0002174119,0.0001297085,0.00007908073,0.0003199062,0.06159873],"genre_scores_gemma":[0.9987957,0.00002584409,0.0004638404,0.00002222189,0.0001099659,0.00008416919,0.00001956541,0.00003347251,0.0004451819],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06375713,"threshold_uncertainty_score":0.9990895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009527932079718747,"score_gpt":0.2516643956089417,"score_spread":0.2421364635292229,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}