{"id":"W4391346144","doi":"10.1021/acscatal.3c05570","title":"Stereoblock vs Stereoblend: Orchestrating Competing Living Coordination Chain Transfer Polymerizations for the One-Pot Production of New Viscoelastic Grades of Poly(4-methyl-1-pentene)","year":2024,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"National Science Foundation","keywords":"Tacticity; Polymerization; Viscoelasticity; Polymer chemistry; Cyclopentadienyl complex; Materials science; Chain transfer; Monomer; Copolymer; Molar mass; Brittleness; Catalysis; Polymer; Chemistry; Organic chemistry; Composite material; Radical polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001416032,0.0003921877,0.000141106,0.000125619,0.00009294762,0.0002591192,0.0002625475,0.0002684373,0.00131811],"category_scores_gemma":[0.0001869217,0.0001733255,0.0001186123,0.0001413155,0.0002114438,0.000423182,0.000318611,0.0005222308,0.0003660483],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003225355,"about_ca_system_score_gemma":0.0001843631,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002489924,"about_ca_topic_score_gemma":0.0007646741,"domain_scores_codex":[0.9998877,0.00001172814,0.00000688479,0.0000405616,0.00002728079,0.00002583684],"domain_scores_gemma":[0.9998978,0.00002298298,0.00004014067,0.00001194979,0.000007049467,0.00001996137],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003974671,0.00003057672,0.00005812694,0.00003287914,0.000003006502,0.00002843922,0.00002745372,0.000264198,0.9956245,0.0005655909,0.00003779414,0.00328777],"study_design_scores_gemma":[0.000008833626,0.0001061272,0.0002088162,0.000001412111,0.000002268332,0.00002974584,0.000005502806,0.001854495,0.996972,0.00005178569,0.0007551199,0.000003974841],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9762129,0.0003499207,0.01923451,0.00006175708,0.00002358997,0.00008552537,0.0001114395,0.0002742482,0.003646091],"genre_scores_gemma":[0.9907216,0.0002217445,0.006949578,0.00002317597,0.000004857615,0.00004978212,0.00006383183,0.0000378773,0.001927521],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00131811,"threshold_uncertainty_score":0.004409492,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03778570797608408,"score_gpt":0.2532337466461262,"score_spread":0.2154480386700421,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}