{"id":"W4391607234","doi":"10.1002/cjce.25203","title":"Production of esters with numerous applications: Kinetics of Dowex <scp>50W</scp> catalyzed transesterification of methyl acetate with three‐ and four‐carbon structured alcohols","year":2024,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Thermal and Kinetic Analysis","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Kuwait University","keywords":"Transesterification; Chemistry; Catalysis; Methyl acetate; Alcohol; Limiting; Butanol; Branching (polymer chemistry); Kinetics; Steric effects; Organic chemistry; Ethanol","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003009062,0.0005636046,0.0002688007,0.000271318,0.0001606287,0.0002711365,0.0002296589,0.0002549294,0.0009764057],"category_scores_gemma":[0.0003290046,0.0001752658,0.0003773943,0.0002939877,0.000125819,0.0003888232,0.0001422665,0.000370909,0.0004820813],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003452566,"about_ca_system_score_gemma":0.0003061777,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002231725,"about_ca_topic_score_gemma":0.003345967,"domain_scores_codex":[0.9998265,0.00002804249,0.00001432176,0.00003356167,0.00005973134,0.00003786814],"domain_scores_gemma":[0.9999025,0.00002674723,0.00002003045,0.00001030476,0.00002552657,0.00001497753],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001465705,0.00002256019,0.0003818828,0.00008711843,0.00001142962,0.00005175728,0.00002361196,0.0004211701,0.9951972,0.00007660042,0.00003517084,0.003545085],"study_design_scores_gemma":[0.000002907537,0.00007928293,0.0008916379,0.000003694673,0.000007226786,0.00003043658,0.0000115694,0.00153355,0.9970223,0.00001343223,0.0004002586,0.000003672167],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990344,0.002029144,0.005364192,0.00005353005,0.00002332645,0.000034592,0.0003279013,0.00007237983,0.001750929],"genre_scores_gemma":[0.9949152,0.000897237,0.002192766,0.000009000631,0.000002931097,0.00001797566,0.000264815,0.00001373706,0.001686299],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002231725,"threshold_uncertainty_score":0.004437447,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008141520396449274,"score_gpt":0.1864929618738765,"score_spread":0.1783514414774273,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}