{"id":"W4391611780","doi":"10.1002/adsc.202301383","title":"Tandem Hydrogen‐Borrowing Dehydrogenative Coupling and Hydrodefluorination","year":2024,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Chemistry; Tandem; Coupling (piping); Hydrogen; Photochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004483836,0.000410535,0.0005074276,0.0005712434,0.0003366756,0.0001741284,0.0002877662,0.0001917566,0.0006745904],"category_scores_gemma":[0.0006373399,0.0004103846,0.0003475167,0.001604525,0.0001220611,0.0007259544,0.0001246257,0.0002762581,0.0001750816],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003122389,"about_ca_system_score_gemma":0.00006794617,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002940266,"about_ca_topic_score_gemma":0.00001658205,"domain_scores_codex":[0.9973661,0.00002398249,0.0005637002,0.0009750007,0.0006035043,0.0004676792],"domain_scores_gemma":[0.99813,0.0008612183,0.0001488793,0.0005298469,0.0001097451,0.0002202624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003746919,0.0001613197,0.001058442,0.0003865107,0.001974569,0.0001589957,0.001355277,0.006191718,0.4100533,0.001886272,0.00007386201,0.5766623],"study_design_scores_gemma":[0.0002040944,0.000008689829,0.00003375486,0.0001666023,0.0008036654,0.00003712158,0.0008186132,0.1074179,0.878368,0.0004796567,0.01107646,0.0005854901],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9680616,0.01253314,0.004397505,0.0003234393,0.0001072436,0.0001224726,0.00005761155,0.0007706127,0.01362636],"genre_scores_gemma":[0.9967794,0.0007761967,0.0006680117,0.00004543196,0.0001252527,0.0001806068,0.0001476584,0.00009052493,0.001186872],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5760768,"threshold_uncertainty_score":0.9998348,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008535312012789308,"score_gpt":0.2446014320246035,"score_spread":0.2360661200118142,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}