{"id":"W4391790399","doi":"10.1039/d4cc00044g","title":"Visible-light-induced catalyst-free reductive coupling of aldehydes, ketones and imines with cyanopyridines","year":2024,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Higher Education Discipline Innovation Project; Science and Technology Department of Gansu Province; National Natural Science Foundation of China; Fundamental Research Funds for the Central Universities; International Joint Research Center for Green Catalysis and Synthesis","keywords":"Catalysis; Chemistry; Surface modification; Combinatorial chemistry; Organic chemistry; Pyridine; Aldehyde","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001601738,0.0005047459,0.0001727737,0.0002164041,0.0001706925,0.0001956633,0.0004771668,0.0002591639,0.001745016],"category_scores_gemma":[0.0001609293,0.0001624133,0.0002075151,0.0001758093,0.0002180881,0.0003331828,0.0003465493,0.0005427711,0.0005259018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003322671,"about_ca_system_score_gemma":0.0002883479,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000538327,"about_ca_topic_score_gemma":0.001315608,"domain_scores_codex":[0.9998446,0.00001685957,0.00001007585,0.00003649319,0.00004269747,0.00004923075],"domain_scores_gemma":[0.9999409,0.000009093244,0.00001768105,0.000008183532,0.00001201107,0.000012174],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006221173,0.00002157419,0.00007704016,0.0002637656,0.00001040674,0.0002260388,0.00006946908,0.0003887807,0.988018,0.002033079,0.0002307446,0.008598928],"study_design_scores_gemma":[0.000007748635,0.0001534102,0.0002813208,0.000009144134,0.000009251843,0.0001995308,0.00001541119,0.0004527191,0.9920865,0.0001131607,0.006661175,0.00001055074],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9003872,0.008626286,0.06023448,0.0003587122,0.0002911717,0.0001677537,0.0006995276,0.0006083873,0.02862641],"genre_scores_gemma":[0.979734,0.003244826,0.01198186,0.00006485633,0.00004303101,0.00004367793,0.0002949095,0.00005503277,0.004537884],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001745016,"threshold_uncertainty_score":0.005837679,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02640307204742584,"score_gpt":0.285959053427035,"score_spread":0.2595559813796091,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}