{"id":"W4391790399","doi":"10.1039/d4cc00044g","title":"Visible-light-induced catalyst-free reductive coupling of aldehydes, ketones and imines with cyanopyridines","year":2024,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Higher Education Discipline Innovation Project; Science and Technology Department of Gansu Province; National Natural Science Foundation of China; Fundamental Research Funds for the Central Universities; International Joint Research Center for Green Catalysis and Synthesis","keywords":"Catalysis; Chemistry; Surface modification; Combinatorial chemistry; Organic chemistry; Pyridine; Aldehyde","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009552047,0.0002425144,0.0003286483,0.00008684626,0.0001444121,0.00006720159,0.001123458,0.0001876098,0.00006567162],"category_scores_gemma":[0.0005753826,0.0002038484,0.00009603531,0.0004765919,0.0005881051,0.0001971995,0.0006085152,0.000582315,0.000008592463],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009895395,"about_ca_system_score_gemma":0.0001121482,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001435992,"about_ca_topic_score_gemma":0.00001622191,"domain_scores_codex":[0.9986781,0.000008187281,0.0004153551,0.0003999644,0.0002503668,0.0002480333],"domain_scores_gemma":[0.9964404,0.0008889788,0.0001034403,0.002204631,0.0001709884,0.0001916123],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002795778,0.0001348021,0.00006601172,0.0002541364,0.0001293305,0.000002133791,0.0002243178,0.000001836686,0.9956653,0.002544183,0.0006094118,0.0003405853],"study_design_scores_gemma":[0.0002653297,0.00001540154,0.00001546097,0.000419412,0.0001649536,0.00004952243,0.0003111138,0.00209857,0.9901314,0.002564694,0.003719073,0.0002450394],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.977406,0.003783101,0.00003426045,0.0046461,0.0000338639,0.0001547267,0.00008686591,0.000290983,0.01356412],"genre_scores_gemma":[0.9962662,0.0004015523,0.002659963,0.00001818571,0.00008700132,0.0001479229,0.0001615154,0.00005022399,0.0002074448],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01886021,"threshold_uncertainty_score":0.8312695,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02640307204742584,"score_gpt":0.285959053427035,"score_spread":0.2595559813796091,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}