{"id":"W4391805621","doi":"10.1139/cjc-2023-0162","title":"Investigating colossal thermal expansion driven by chalcogen bonds using AB(XCN)<sub>4</sub> (A = Co, Zn, Cd; B = Cd, Hg; X = S, Se) compounds","year":2024,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Thermal Expansion and Ionic Conductivity","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chalcogen; Thermal expansion; Crystallography; Negative thermal expansion; Thermal; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001113636,0.0003514116,0.0002446892,0.0001527263,0.0002125324,0.0002167603,0.0002345132,0.000208484,0.001650632],"category_scores_gemma":[0.0002105668,0.0001704022,0.0001323761,0.0002029914,0.0003193762,0.0002017507,0.0002374851,0.0003210017,0.0001503098],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003147673,"about_ca_system_score_gemma":0.0001584359,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001735159,"about_ca_topic_score_gemma":0.003217137,"domain_scores_codex":[0.9999039,0.00001153761,0.000002789921,0.00002290924,0.00003658363,0.00002234664],"domain_scores_gemma":[0.9999185,0.00002881809,0.00001957624,0.000005166738,0.00001828767,0.000009752952],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001567674,0.00001315166,0.0005520436,0.0001408248,0.0000171774,0.00008145536,0.00005667151,0.001107606,0.9954656,0.0001745394,0.00008764323,0.002146611],"study_design_scores_gemma":[0.00001713027,0.0002937199,0.00592957,0.00001208966,0.0000208701,0.000170515,0.0001001015,0.004470882,0.9868523,0.00005689472,0.002061042,0.00001482739],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981582,0.0004576977,0.0003811957,0.00002340818,0.000007891874,0.00000643529,0.00006992176,0.00001901772,0.0008763951],"genre_scores_gemma":[0.9984341,0.0003288279,0.0005713254,0.00001221916,0.000004240126,0.0000139117,0.00008297842,0.00002011495,0.000532247],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001735159,"threshold_uncertainty_score":0.005521894,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02551503276558457,"score_gpt":0.2555352649094234,"score_spread":0.2300202321438388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}