{"id":"W4391995984","doi":"10.3762/bjoc.20.35","title":"Mechanisms for radical reactions initiating from <i>N</i>-hydroxyphthalimide esters","year":2024,"lang":"en","type":"article","venue":"Beilstein Journal of Organic Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Mitacs","keywords":"Chemistry; Reactivity (psychology); Combinatorial chemistry; Lewis acids and bases; Electron transfer; Radical ion; Fragmentation (computing); Radical cyclization; Redox; Brønsted–Lowry acid–base theory; Organic chemistry; Catalysis; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002988097,0.0003031405,0.0004428308,0.00005186384,0.0001290595,0.0001705607,0.0005026694,0.0003720018,0.005792927],"category_scores_gemma":[0.001475367,0.0002904389,0.0004822539,0.0002480485,0.0001216531,0.0002773305,0.00006702373,0.00107874,0.00002543953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004422456,"about_ca_system_score_gemma":0.0004479799,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001353423,"about_ca_topic_score_gemma":9.14153e-7,"domain_scores_codex":[0.9976008,0.00001473581,0.001064197,0.0003871996,0.0005299544,0.0004031401],"domain_scores_gemma":[0.9973246,0.001317552,0.0003883249,0.0003643162,0.0001453716,0.0004598311],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005098843,0.0001060456,0.00001020842,0.0003566791,0.0002940156,0.0001547153,0.00008993198,0.000007083585,0.9956361,0.00007447592,0.001939276,0.001280479],"study_design_scores_gemma":[0.000739689,0.0000264335,0.000003134073,0.0008412576,0.0002696052,0.001064837,0.0003312514,0.0005299594,0.9593577,0.008471671,0.02807197,0.000292463],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9534459,0.002168991,0.0280987,0.002338619,0.001075383,0.0001857667,0.000359147,0.0003582213,0.01196924],"genre_scores_gemma":[0.9915673,0.00007420123,0.00571407,0.0001068539,0.001297401,0.00002221213,0.00008048727,0.0001105561,0.001026911],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03812138,"threshold_uncertainty_score":0.9999548,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01433977984347278,"score_gpt":0.2584018544643303,"score_spread":0.2440620746208575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}