{"id":"W4391996107","doi":"10.1021/acs.macromol.3c01634","title":"Regulating the Tautomerization in Covalent Organic Frameworks for Efficient Sacrificial Agent-Free Photocatalytic H<sub>2</sub>O<sub>2</sub> Production","year":2024,"lang":"en","type":"article","venue":"Macromolecules","topic":"Covalent Organic Framework Applications","field":"Materials Science","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Science and Technology Program of Hunan Province; Natural Science Foundation of Hunan Province; National Natural Science Foundation of China","keywords":"Tautomer; Photocatalysis; Chemistry; Covalent bond; Imine; Reagent; Adsorption; Enol; Photochemistry; Enamine; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001153228,0.0004165295,0.0003447745,0.0002686324,0.0004927645,0.0005027545,0.0008080748,0.0003637908,0.0000579127],"category_scores_gemma":[0.001180953,0.0003702875,0.000167174,0.001652706,0.0002568929,0.0001621798,0.0003529641,0.0006360685,0.0003370194],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004514464,"about_ca_system_score_gemma":0.0002411411,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001344715,"about_ca_topic_score_gemma":0.00008701643,"domain_scores_codex":[0.9964601,0.0001736797,0.000807507,0.00117277,0.0006633564,0.0007226262],"domain_scores_gemma":[0.9978054,0.0003731082,0.0002344647,0.001312921,0.0001694402,0.0001047245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004360814,0.0001592789,0.00001779517,0.0002333193,0.00002219951,0.000008739446,0.001055469,0.003715317,0.9820113,0.002141673,0.0008987187,0.009692536],"study_design_scores_gemma":[0.0002778083,0.0000590647,0.0004170294,0.0003866274,0.0001022039,0.00004071101,0.0002850046,0.02370989,0.9699587,0.003996115,0.0003599644,0.0004068699],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8987098,0.0005579343,0.09295594,0.002735403,0.001837815,0.002602151,0.00008916033,0.0004844796,0.00002731613],"genre_scores_gemma":[0.9967048,0.00007475114,0.001313571,0.000207648,0.0005647445,0.0008643248,0.0001121362,0.000139234,0.00001884688],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09799495,"threshold_uncertainty_score":0.9998749,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01066642285321016,"score_gpt":0.2441687327489635,"score_spread":0.2335023098957534,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}