{"id":"W4392053879","doi":"10.2174/0115701794273947231206111750","title":"An Alternative Method for the Selective Synthesis of Ortho-nitro Anilines Using Bismuth Nitrate Pentahydrate","year":2024,"lang":"en","type":"article","venue":"Current Organic Synthesis","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Consejo Nacional de Ciencia y Tecnología","keywords":"Nitration; Chemistry; Reagent; Bismuth; Acetic anhydride; Nitric acid; Nitro; Organic chemistry; Nitrate; Sulfuric acid; Regioselectivity; Combinatorial chemistry; Inorganic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005515906,0.0003998832,0.0005375263,0.0001274702,0.0003049544,0.0001341042,0.0005354278,0.0001593913,0.001209774],"category_scores_gemma":[0.001197721,0.0002701,0.0004336877,0.0005119888,0.0001418879,0.0002217194,0.00007417602,0.0003336111,0.00001647018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002244808,"about_ca_system_score_gemma":0.0002121485,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001280698,"about_ca_topic_score_gemma":0.00002732761,"domain_scores_codex":[0.9978335,0.0001213178,0.0005755259,0.0006929296,0.0003387786,0.0004379198],"domain_scores_gemma":[0.9924065,0.006454597,0.000245868,0.0005416687,0.0002080506,0.0001432664],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005854546,0.0002666818,0.0001235956,0.0004374574,0.0005640319,0.000001939045,0.0003178156,0.00004897681,0.8976558,0.0002351646,0.0001212176,0.1001687],"study_design_scores_gemma":[0.00008984795,0.00001251618,0.00003279061,0.0005180531,0.001179307,0.00002121022,0.0007660495,0.0447095,0.9491604,0.0006138319,0.002565583,0.0003309099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8933679,0.01016583,0.08815586,0.0008066463,0.001880262,0.001018276,0.001855283,0.0007038594,0.002046025],"genre_scores_gemma":[0.9956257,0.0005125348,0.002703191,0.000009940774,0.0007211284,0.0002329006,0.0000123517,0.0001155838,0.00006668594],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1022577,"threshold_uncertainty_score":0.9999751,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0453316474174446,"score_gpt":0.3498588692183537,"score_spread":0.3045272218009091,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}