{"id":"W4392291618","doi":"10.1002/anie.202402912","title":"Photocatalytic <i>O</i>‐ to <i>S</i>‐Rearrangement of Tertiary Cyclopropanols","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; University of Toronto; Canada Foundation for Innovation; Alfred P. Sloan Foundation","keywords":"Photocatalysis; Chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001100547,0.000229491,0.0000864914,0.0001266631,0.000132223,0.0001329368,0.0002062608,0.0001457846,0.002441298],"category_scores_gemma":[0.0001325174,0.00006470545,0.0001816157,0.0001282028,0.0002191029,0.0001934635,0.0001384433,0.0003713849,0.0003476592],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002555594,"about_ca_system_score_gemma":0.0002150425,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007447,"about_ca_topic_score_gemma":0.001890999,"domain_scores_codex":[0.9999276,0.000005623682,0.000003583836,0.00001391662,0.00001531857,0.0000338981],"domain_scores_gemma":[0.9999529,0.00001121466,0.00001581271,0.000006336219,0.000006806867,0.000006890809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007512089,0.00003256032,0.0002110952,0.0001296338,0.000007692635,0.0001841276,0.00008591831,0.0003794766,0.9897612,0.001857029,0.0004632731,0.00681287],"study_design_scores_gemma":[0.000005527245,0.0001399594,0.0005490925,0.000005570441,0.000004609465,0.00009491772,0.00003094461,0.000592028,0.9955797,0.000149529,0.002842635,0.000005454157],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9664718,0.001633969,0.008486543,0.0003395399,0.0001105462,0.00004925753,0.0002297066,0.0002142277,0.02246451],"genre_scores_gemma":[0.995561,0.000771056,0.001227535,0.00004996841,0.0000100591,0.00001207262,0.00006097034,0.00001838191,0.002288868],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002441298,"threshold_uncertainty_score":0.008166909,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01137846036315794,"score_gpt":0.2687625830122408,"score_spread":0.2573841226490828,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}