{"id":"W4392348862","doi":"10.1021/jacs.4c00757","title":"Stable Interfacial Ruthenium Species for Highly Efficient Polyolefin Upcycling","year":2024,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Nanomaterials for catalytic reactions","field":"Chemistry","cited_by":91,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"National Natural Science Foundation of China","keywords":"Polyolefin; Chemistry; Hydrogenolysis; Catalysis; Ruthenium; Ligand (biochemistry); Bond cleavage; Rate-determining step; Photochemistry; Polymer chemistry; Chemical engineering; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001290141,0.0002822501,0.0001532801,0.0001644962,0.0001159412,0.0002620289,0.0002814995,0.0002618646,0.00194228],"category_scores_gemma":[0.0002019549,0.000100051,0.0001426893,0.0001406109,0.0001330102,0.0003376065,0.0002193582,0.0005530074,0.0006048008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001642503,"about_ca_system_score_gemma":0.00009515895,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001514021,"about_ca_topic_score_gemma":0.0004590078,"domain_scores_codex":[0.9998982,0.00001426159,0.000007935575,0.00002290924,0.00002609144,0.00003050058],"domain_scores_gemma":[0.9999387,0.00001464554,0.00001639441,0.00001412621,0.00001035395,0.000005724806],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001973672,0.00002021233,0.00007468304,0.00005566951,0.000003624438,0.00004334264,0.00001850293,0.0002463414,0.9942203,0.0006051808,0.00006374147,0.004628604],"study_design_scores_gemma":[0.000001698297,0.00004508558,0.000112806,0.000002345204,0.000002987146,0.00003886961,0.00000606932,0.0006466084,0.9979121,0.0000393114,0.001189755,0.00000238003],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9514664,0.001269337,0.03961977,0.0001262639,0.00004092354,0.00006775974,0.0001385294,0.0005333021,0.00673774],"genre_scores_gemma":[0.9905843,0.000309827,0.007512946,0.00002746197,0.000005835582,0.00002026893,0.00007882741,0.00004399691,0.001416605],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00194228,"threshold_uncertainty_score":0.006497562,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01331022410069426,"score_gpt":0.2585946706615979,"score_spread":0.2452844465609036,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}