{"id":"W4392380142","doi":"10.1002/chem.202400642","title":"Redox‐Neutral Multicatalytic Cerium Photoredox‐Enabled Cleavage of O−H Bearing Substrates","year":2024,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Network for Innovation in Education; University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Cleavage (geology); Cerium; Redox; Chemistry; Photochemistry; Inorganic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002245198,0.0003027716,0.0002189211,0.0001049609,0.0001002534,0.0002338349,0.0003511523,0.0003451081,0.0009063818],"category_scores_gemma":[0.000194636,0.0001431472,0.0001898812,0.00009862438,0.0002534268,0.0003950935,0.0002710631,0.0005463671,0.0002587262],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002345948,"about_ca_system_score_gemma":0.0001714092,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004312063,"about_ca_topic_score_gemma":0.0009464965,"domain_scores_codex":[0.9998715,0.00000829584,0.000008102939,0.00004383747,0.00002276454,0.00004545006],"domain_scores_gemma":[0.9999048,0.00001507768,0.00003398291,0.0000162822,0.00001288219,0.00001705661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000300384,0.000007741592,0.00004557187,0.00004028912,0.000003445771,0.00005077232,0.00001732329,0.00008099965,0.9981484,0.0001826517,0.00002951781,0.001363287],"study_design_scores_gemma":[0.000002375431,0.00003594231,0.0001137763,0.00000112146,0.00000209862,0.00004814284,0.000006706539,0.0001323122,0.999071,0.00001678379,0.0005677773,0.000001890503],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9837352,0.001283407,0.01089601,0.0001418513,0.00004311577,0.00003919485,0.0001448314,0.0001309127,0.003585455],"genre_scores_gemma":[0.9929895,0.0004606962,0.004629192,0.00004304939,0.000004769386,0.00001173263,0.0001184443,0.00002510091,0.001717489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009063818,"threshold_uncertainty_score":0.003032148,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0231321502437783,"score_gpt":0.2653318976681015,"score_spread":0.2421997474243232,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}