{"id":"W4392396230","doi":"10.1039/d4dt00251b","title":"Triple <i>para</i>-substitution reactions of B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> and [(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>PF]<sup>+</sup> with P(SiMe<sub>3</sub>)<sub>3</sub>","year":2024,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Substitution (logic); Crystallography; Chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009267336,0.00044483,0.0002263731,0.0001088201,0.0002718945,0.0002543627,0.0002725776,0.0002593389,0.006341445],"category_scores_gemma":[0.0001961002,0.0001942765,0.000165366,0.0001195588,0.0002930279,0.000371602,0.000330997,0.0004459037,0.001202991],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002026574,"about_ca_system_score_gemma":0.000263899,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001224349,"about_ca_topic_score_gemma":0.00191545,"domain_scores_codex":[0.9999146,0.000007928867,0.000002916594,0.00001690116,0.00002185434,0.00003583432],"domain_scores_gemma":[0.9999313,0.000008550184,0.00001838354,0.000009995969,0.00001242573,0.00001936291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004853594,0.00002324569,0.0002065094,0.0001026879,0.00001193498,0.000176537,0.00009560886,0.0002701628,0.9887184,0.002098587,0.0005645443,0.007246529],"study_design_scores_gemma":[0.000009646616,0.0001519187,0.0003572889,0.000003376706,0.000007910563,0.0001815182,0.00002828444,0.0003468982,0.9951871,0.0002026479,0.003516203,0.0000072168],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9341859,0.0006687466,0.02583394,0.0002203169,0.0002283868,0.00008691257,0.0003497298,0.0004715451,0.03795448],"genre_scores_gemma":[0.9817581,0.0003479807,0.005832262,0.00008000099,0.000009501074,0.00003135224,0.0002354302,0.0001371169,0.01156845],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006341445,"threshold_uncertainty_score":0.02121431,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01039141576750442,"score_gpt":0.2194092193302446,"score_spread":0.2090178035627402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}