{"id":"W4392459570","doi":"10.26434/chemrxiv-2024-d7znt","title":"Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks","year":2024,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Covalent Organic Framework Applications","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University; McGill University","funders":"Fonds de recherche du Québec – Nature et technologies; Leverhulme Trust; Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Mechanochemistry; Mechanosynthesis; Covalent bond; Raman spectroscopy; Crystallinity; Porosity; Chemical engineering; Materials science; Solvent; Nanotechnology; Chemistry; Organic chemistry; Ball mill; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000729171,0.0003087752,0.0001358129,0.000152078,0.0001547384,0.000224893,0.0002671846,0.0002320054,0.0009952674],"category_scores_gemma":[0.0001105617,0.0001116522,0.0001771827,0.0001239115,0.0001423459,0.0001912755,0.0002699626,0.0003036651,0.0002102103],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002893994,"about_ca_system_score_gemma":0.0001573027,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005449025,"about_ca_topic_score_gemma":0.001809636,"domain_scores_codex":[0.9999069,0.000004877849,0.000003327667,0.00002364027,0.00002596658,0.00003524355],"domain_scores_gemma":[0.9999672,0.000005594132,0.000009884353,0.000004540517,0.000004424149,0.000008305357],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001579269,0.00001439315,0.0000827527,0.00007482125,0.00000803468,0.00005791771,0.00001784116,0.0005196227,0.9921589,0.0009233624,0.00007806236,0.006048365],"study_design_scores_gemma":[0.000004490914,0.00006911372,0.0004690104,0.000003699491,0.000004512466,0.00008250432,0.00001010417,0.0009332271,0.9933442,0.00009869842,0.004971955,0.000008515303],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9554129,0.004254265,0.03124197,0.000191674,0.0001349602,0.00008698618,0.0003411465,0.0004256851,0.007910413],"genre_scores_gemma":[0.9857333,0.0009413697,0.01121866,0.00003813504,0.00001379231,0.00003827561,0.0001200716,0.00002249311,0.001873947],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009952674,"threshold_uncertainty_score":0.003329515,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01542549067652776,"score_gpt":0.2647799968831581,"score_spread":0.2493545062066303,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}