{"id":"W4392523400","doi":"10.1039/d4re00009a","title":"A scalable continuous photo-flow protocol for anaerobic oxidative cleavage of styrenes","year":2024,"lang":"en","type":"article","venue":"Reaction Chemistry & Engineering","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Science and Engineering Research Board; Bristol-Myers Squibb Canada; Council of Scientific and Industrial Research, India","keywords":"Oxidative cleavage; Cleavage (geology); Anaerobic exercise; Oxidative phosphorylation; Chemistry; Reagent; Protocol (science); Continuous flow; Oxygen; Photochemistry; Combinatorial chemistry; Organic chemistry; Materials science; Catalysis; Biochemistry; Biochemical engineering; Biology; Engineering; Medicine","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008440233,0.0002189776,0.0002702792,0.00003250991,0.00004517008,0.000047754,0.0001140417,0.0001960927,0.0004227759],"category_scores_gemma":[0.0001227822,0.0002086783,0.0002109199,0.0001659682,0.00003065497,0.0001261903,0.00002647299,0.000241075,0.000006914652],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001647753,"about_ca_system_score_gemma":0.00004751638,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002394999,"about_ca_topic_score_gemma":4.728944e-7,"domain_scores_codex":[0.9989146,0.00000199877,0.0003360344,0.0003367029,0.000153338,0.00025732],"domain_scores_gemma":[0.999319,0.0001989629,0.00008597969,0.0002351727,0.00006513691,0.00009571523],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003307934,0.0000823524,0.000006992851,0.002088919,0.0001012733,0.0000027534,0.00002716255,0.0002023706,0.9932798,0.00002394071,0.0009709509,0.003180372],"study_design_scores_gemma":[0.0002769039,0.000006248794,0.000005242163,0.0005118621,0.00003613266,0.00001995757,0.00005257068,0.007963005,0.827574,0.00001049377,0.1633615,0.0001820376],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7811655,0.0007169,0.01996794,0.0004710231,0.001018421,0.06364896,0.001024219,0.005309804,0.1266773],"genre_scores_gemma":[0.8680833,0.00002307797,0.004403858,0.000006339965,0.001102612,0.1200213,0.0001441687,0.0001743471,0.006041014],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1657058,"threshold_uncertainty_score":0.8509655,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01248943240039141,"score_gpt":0.2554671936604166,"score_spread":0.2429777612600252,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}