{"id":"W4392748927","doi":"10.1002/cctc.202400110","title":"Modern Cyclopropanation via Non‐Traditional Building Blocks","year":2024,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Cyclopropanation; Chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009698363,0.0002573429,0.0001847202,0.0001017087,0.0001171148,0.0001243535,0.0002240138,0.0002156414,0.001792363],"category_scores_gemma":[0.00002544907,0.0002707735,0.0001552485,0.0002380048,0.00004273711,0.0002342156,0.00005890954,0.0004253376,0.0002728553],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004237184,"about_ca_system_score_gemma":0.0001196109,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000193084,"about_ca_topic_score_gemma":0.000001852995,"domain_scores_codex":[0.998381,0.000004025618,0.0002845619,0.0005603347,0.0004408315,0.0003292722],"domain_scores_gemma":[0.9993008,0.00006855652,0.00006003456,0.0003403646,0.00009061143,0.0001396084],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007514981,0.00004634104,0.00001597915,0.0003064502,0.00004872301,0.00003370331,0.0005229759,0.00002280284,0.9438412,0.0008312473,0.0005411797,0.0537819],"study_design_scores_gemma":[0.0002141363,0.00000744585,0.00001669984,0.0001240826,0.00004887896,0.00014983,0.0001800924,0.01545666,0.962341,0.01049071,0.01065409,0.0003163424],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8754002,0.0008222309,0.03582022,0.0005354434,0.0007184603,0.0001420403,0.0000427092,0.001254524,0.0852642],"genre_scores_gemma":[0.9929278,0.00003032987,0.002844285,0.00005065642,0.001017235,0.00008462819,0.0001916249,0.00007841871,0.002774973],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1175277,"threshold_uncertainty_score":0.9999744,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01790731798121323,"score_gpt":0.2400494323113475,"score_spread":0.2221421143301343,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}