{"id":"W4393043773","doi":"10.1007/s11696-024-03387-5","title":"Extraction, separation, recovery, transportation, ICP-AES trace determination of thorium(IV) with calix[4]resorcinarene-2, 8, 14, 20-tetrakis [N-phenylbenzo]-hydroxamic acid","year":2024,"lang":"en","type":"article","venue":"Chemical Papers","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"Apotex (Canada)","funders":"","keywords":"Resorcinarene; Chemistry; Thorium; Extraction (chemistry); Hydrochloric acid; Nuclear chemistry; Hydroxamic acid; Chromatography; Inorganic chemistry; Organic chemistry; Materials science; Uranium; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006791076,0.0009090928,0.0006845709,0.001106683,0.0009409537,0.0005692017,0.0009580034,0.0005699475,0.004177401],"category_scores_gemma":[0.0008640568,0.0005837348,0.0006741243,0.0007314187,0.0005001515,0.0004698544,0.0005192984,0.000930762,0.003226409],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008250728,"about_ca_system_score_gemma":0.001252834,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003315614,"about_ca_topic_score_gemma":0.004953337,"domain_scores_codex":[0.9992112,0.00006261101,0.00004409703,0.000244751,0.0003686774,0.00006863692],"domain_scores_gemma":[0.9996069,0.00006173358,0.00004612806,0.00008633806,0.0001794935,0.00001950696],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009393018,0.00002671264,0.0002007369,0.0000804791,0.00001447555,0.0000332409,0.00004256623,0.0002099924,0.9907052,0.0002815551,0.0002836768,0.008027497],"study_design_scores_gemma":[0.00001049195,0.00007295567,0.0007975148,0.000006191045,0.00002148998,0.0001127767,0.00001959068,0.00188369,0.989692,0.000245748,0.007128575,0.00000894138],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.3883058,0.001758632,0.5801881,0.0004166384,0.0002559819,0.001137311,0.00453997,0.009555471,0.01384213],"genre_scores_gemma":[0.4906795,0.002619888,0.4551018,0.0003637134,0.00008647772,0.001270317,0.005308126,0.002576593,0.04199366],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.004177401,"threshold_uncertainty_score":0.01397479,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00894651836298681,"score_gpt":0.2727864770911594,"score_spread":0.2638399587281726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}