{"id":"W4393043773","doi":"10.1007/s11696-024-03387-5","title":"Extraction, separation, recovery, transportation, ICP-AES trace determination of thorium(IV) with calix[4]resorcinarene-2, 8, 14, 20-tetrakis [N-phenylbenzo]-hydroxamic acid","year":2024,"lang":"en","type":"article","venue":"Chemical Papers","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"Apotex (Canada)","funders":"","keywords":"Resorcinarene; Chemistry; Thorium; Extraction (chemistry); Hydrochloric acid; Nuclear chemistry; Hydroxamic acid; Chromatography; Inorganic chemistry; Organic chemistry; Materials science; Uranium; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001554216,0.0003713078,0.0003371372,0.00006963589,0.0001347799,0.00009674829,0.0002307719,0.0003032195,0.001301236],"category_scores_gemma":[0.00007448584,0.0003459384,0.0001679884,0.000391389,0.0001756837,0.0005510118,0.000007323526,0.0004330878,0.000009100103],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002103928,"about_ca_system_score_gemma":0.0001639209,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001473001,"about_ca_topic_score_gemma":0.00001923549,"domain_scores_codex":[0.9978693,0.00001991254,0.0005964607,0.0006654996,0.000500203,0.0003486471],"domain_scores_gemma":[0.9989468,0.0002188752,0.0002166031,0.0002981526,0.0001752514,0.0001443339],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002182936,0.00009911639,0.0003793838,0.001132642,0.00009598902,0.00002652537,0.0007013038,0.0001070822,0.9847914,0.00003656195,0.0006945122,0.01171717],"study_design_scores_gemma":[0.0004883621,0.00004278107,0.00009492008,0.0004122092,0.0001968245,0.00003952506,0.0004101297,0.0006837304,0.9824192,0.0003028944,0.01448293,0.0004264953],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9674805,0.001965702,0.00243517,0.00031179,0.0001772876,0.0001393715,0.0001815888,0.0002780691,0.02703046],"genre_scores_gemma":[0.9952867,0.0001061201,0.001204704,0.00003194335,0.0002956993,0.00005770221,0.0005970715,0.00006020443,0.002359874],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02780612,"threshold_uncertainty_score":0.9998993,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00894651836298681,"score_gpt":0.2727864770911594,"score_spread":0.2638399587281726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}