{"id":"W4393071013","doi":"10.26434/chemrxiv-2024-ncvzn","title":"Anharmonic vibrational spectroscopy of germanium-containing clusters, Ge(x)C(4−x) and Ge(x)Si(4−x) (x = 0-4), for interstellar detection","year":2024,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alliance de recherche numérique du Canada","keywords":"Germanium; Spectroscopy; Anharmonicity; X-ray spectroscopy; Physics; Atomic physics; Materials science; Crystallography; Chemistry; Silicon; Astronomy; Condensed matter physics; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001325588,0.0001783749,0.0001299016,0.000197388,0.0001804318,0.000116659,0.0003502315,0.0002673148,0.001270425],"category_scores_gemma":[0.0001295157,0.00006583997,0.00008908772,0.000190778,0.0001445658,0.0002275926,0.0002704469,0.0002641688,0.000128194],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001849773,"about_ca_system_score_gemma":0.0001189613,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005976061,"about_ca_topic_score_gemma":0.001682067,"domain_scores_codex":[0.9999527,0.00000682722,7.639116e-7,0.000009553299,0.00002133151,0.000008906166],"domain_scores_gemma":[0.9999651,0.00001282076,0.000005497326,0.00000520599,0.000006047307,0.0000053287],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.000205636,0.00007154912,0.005469607,0.0004490363,0.00004169282,0.0002335778,0.0002282147,0.02615961,0.9274541,0.009428439,0.001444734,0.02881382],"study_design_scores_gemma":[0.00006932495,0.0007847714,0.03465724,0.00005554057,0.0000638549,0.0003768367,0.0005189518,0.5008523,0.4426278,0.007069031,0.01285326,0.00007108667],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9772297,0.001561512,0.01525144,0.0001819599,0.00003089952,0.00001681712,0.0001575264,0.00009499893,0.005475136],"genre_scores_gemma":[0.9919989,0.0005384946,0.00591443,0.00002607947,0.000007034072,0.00001218304,0.0001622749,0.0000084699,0.001332273],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001270425,"threshold_uncertainty_score":0.00424993,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01561830863583764,"score_gpt":0.2605490987893078,"score_spread":0.2449307901534702,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}