{"id":"W4393143300","doi":"10.1016/j.cca.2024.117890","title":"LC-MS/MS measurement of endogenous steroid hormones and phase II metabolites in blood volumetric absorptive microsampling (VAMS) for doping control purposes","year":2024,"lang":"en","type":"article","venue":"Clinica Chimica Acta","topic":"Biosimilars and Bioanalytical Methods","field":"Immunology and Microbiology","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Ministero dell’Istruzione, dell’Università e della Ricerca; World Anti-Doping Agency; Partnership for Clean Competition","keywords":"Chemistry; Chromatography; Analyte","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001843859,0.0002968033,0.0009348104,0.0003488655,0.0001549176,0.00004656978,0.0002765323,0.0003678129,0.00007593023],"category_scores_gemma":[0.001319286,0.000234871,0.0003033539,0.0003682581,0.000373252,0.00009375181,0.0001430441,0.0004167132,0.000003366127],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002991613,"about_ca_system_score_gemma":0.0001053075,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002907852,"about_ca_topic_score_gemma":0.00001880959,"domain_scores_codex":[0.997516,0.0002667576,0.001016174,0.0006278968,0.00007586675,0.0004973384],"domain_scores_gemma":[0.9974689,0.001785806,0.0002281614,0.0002995862,0.0001623264,0.00005514773],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005065814,0.000845122,0.0006143673,0.0001830968,0.001011871,0.000003131464,0.0002235353,2.215532e-7,0.985339,0.000161352,0.0002542407,0.01085744],"study_design_scores_gemma":[0.01295537,0.003355199,0.003187371,0.0004864278,0.002076161,0.00009446417,0.0001524991,0.0002561395,0.9412082,0.0008423495,0.03478269,0.0006031281],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9476188,0.04822278,0.0004824689,0.001056698,0.0007040729,0.001105417,0.0005742336,0.00006710654,0.000168379],"genre_scores_gemma":[0.9948631,0.002275381,0.002350364,0.0002231456,0.00009146689,0.00006645232,0.00002421305,0.00002989679,0.0000759724],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04724426,"threshold_uncertainty_score":0.9577761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07670242077501588,"score_gpt":0.3328353639135216,"score_spread":0.2561329431385058,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}