{"id":"W4394001610","doi":"10.1039/d3cp06079a","title":"Exploring the ultrafast and isomer-dependent photodissociation of iodothiophenes <i>via</i> site-selective ionization","year":2024,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"SLAC National Accelerator Laboratory; Basic Energy Sciences; Japan Society for the Promotion of Science; Jesus College, University of Oxford; Jesus College, University of Cambridge; Science and Technology Facilities Council; Office of Science; King Saud University; University of Bristol; U.S. Department of Energy; European Research Council; Lincoln College, University of Oxford; Leverhulme Trust; University of Southampton; Engineering and Physical Sciences Research Council; University of Oxford; Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation","keywords":"Dissociation (chemistry); Photodissociation; Chemistry; Coulomb explosion; Ionization; Photoexcitation; Kinetic energy; Atomic physics; Ion; Extreme ultraviolet; Molecule; Photochemistry; Excited state; Physics; Physical chemistry; Laser","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009168404,0.0002569349,0.00006424629,0.0001083921,0.0001190135,0.0002419983,0.0002802054,0.0002030253,0.001856115],"category_scores_gemma":[0.0001330291,0.0001227096,0.0001161991,0.0001643382,0.0002186634,0.0002261481,0.0001979972,0.0002879611,0.0002186726],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002282238,"about_ca_system_score_gemma":0.0001600701,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006959782,"about_ca_topic_score_gemma":0.0009757032,"domain_scores_codex":[0.9999379,0.000006246315,0.000001124419,0.00001902164,0.0000133344,0.00002243776],"domain_scores_gemma":[0.9999578,0.00001287806,0.00001398805,0.000005956161,0.000005472957,0.000003970002],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009377856,0.0000149305,0.0005291325,0.00005904711,0.00000564859,0.00008054743,0.00006176245,0.0002230166,0.9938279,0.0009697388,0.0001112266,0.004023287],"study_design_scores_gemma":[0.000003353232,0.00005832837,0.001337217,0.0000022283,0.000004024642,0.00008831552,0.00002956778,0.001144334,0.9963163,0.00008429329,0.0009288688,0.000003240435],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910396,0.0004002121,0.004485149,0.0000568991,0.000008241465,0.000009681544,0.0001362295,0.00006975639,0.003794183],"genre_scores_gemma":[0.9967961,0.0003316031,0.001292811,0.00002123645,0.000002188237,0.000006397207,0.00008921988,0.00001270383,0.001447847],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001856115,"threshold_uncertainty_score":0.006209314,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02028437348159823,"score_gpt":0.2436866296042998,"score_spread":0.2234022561227015,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}