{"id":"W4394821677","doi":"10.1021/acs.organomet.4c00070","title":"C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Reductive Elimination from (Phenoxyimine)Cobalt(III)(CH<sub>3</sub>)<sub>2</sub>(PMe<sub>3</sub>)<sub>2</sub> Complexes","year":2024,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Bristol-Myers Squibb Foundation","keywords":"Chemistry; Reductive elimination; Cobalt; Trimethylphosphine; Medicinal chemistry; Steric effects; Disproportionation; Phosphine; Substituent; Stereochemistry; Inorganic chemistry; Crystal structure; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000138349,0.0002542909,0.0001508758,0.00005314507,0.00008276562,0.0001497723,0.0002254434,0.0001517657,0.0007283489],"category_scores_gemma":[0.0001734574,0.0001136678,0.0001091257,0.00007200562,0.0001503902,0.0001254696,0.0001660104,0.0002923448,0.0003013558],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001789954,"about_ca_system_score_gemma":0.0001371952,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004572137,"about_ca_topic_score_gemma":0.0009997169,"domain_scores_codex":[0.9999038,0.00001344216,0.000007428785,0.00001736561,0.00002669833,0.00003128274],"domain_scores_gemma":[0.9999299,0.00001208501,0.00002324621,0.000006825691,0.00001633103,0.00001165678],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001038041,0.0000085477,0.0001545829,0.00008777797,0.000005467316,0.00003507412,0.00002125826,0.0002101694,0.9975533,0.000149738,0.00008934404,0.001580972],"study_design_scores_gemma":[0.000004645568,0.00008921286,0.000569305,0.000001719838,0.000003497711,0.00008657608,0.0000104694,0.0003537259,0.9975554,0.00001676116,0.001306782,0.000002050557],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9867351,0.0007253872,0.009041159,0.0001058222,0.00001892175,0.00004422431,0.0002219779,0.00009656843,0.00301093],"genre_scores_gemma":[0.9921102,0.0004436709,0.005521561,0.00004322394,0.00000481299,0.00002665752,0.0002937807,0.00002570116,0.001530232],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007283489,"threshold_uncertainty_score":0.002436519,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01294674143635049,"score_gpt":0.2279743417600365,"score_spread":0.215027600323686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}