{"id":"W4394821677","doi":"10.1021/acs.organomet.4c00070","title":"C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Reductive Elimination from (Phenoxyimine)Cobalt(III)(CH<sub>3</sub>)<sub>2</sub>(PMe<sub>3</sub>)<sub>2</sub> Complexes","year":2024,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Bristol-Myers Squibb Foundation","keywords":"Chemistry; Reductive elimination; Cobalt; Trimethylphosphine; Medicinal chemistry; Steric effects; Disproportionation; Phosphine; Substituent; Stereochemistry; Inorganic chemistry; Crystal structure; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"category_scores_codex":[0.001951071,0.003731365,0.003675708,0.003123683,0.001724661,0.001817499,0.003194772,0.002533365,0.001221854],"category_scores_gemma":[0.00182108,0.004113481,0.002471955,0.009817343,0.001384835,0.002729209,0.001666616,0.003473643,0.005789284],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003066483,"about_ca_system_score_gemma":0.001444202,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001788178,"about_ca_topic_score_gemma":0.0001881959,"domain_scores_codex":[0.9809774,0.0007156931,0.004403451,0.005558419,0.004595361,0.003749657],"domain_scores_gemma":[0.9882959,0.00182543,0.001816447,0.004098769,0.001824574,0.002138859],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003213626,0.001537381,0.0002990778,0.000780193,0.003370918,0.0003865631,0.004872464,0.002952809,0.8878191,0.001898646,0.008913441,0.08684802],"study_design_scores_gemma":[0.003399323,0.0002647902,0.0006909698,0.0005275423,0.002940526,0.0002517132,0.004719305,0.02775119,0.9401331,0.00215079,0.01292955,0.004241207],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9755636,0.004853289,0.003913554,0.001928038,0.001118427,0.001644219,0.003047027,0.002510865,0.005420912],"genre_scores_gemma":[0.9774705,0.003877262,0.0006042418,0.000942812,0.003435416,0.0006423894,0.0113004,0.001199965,0.0005270591],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08260681,"threshold_uncertainty_score":0.9996912,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01294674143635049,"score_gpt":0.2279743417600365,"score_spread":0.215027600323686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}