{"id":"W4394834021","doi":"10.1139/cjp-2023-0301","title":"Dielectric and hydrogen bonding studies of butyronitrile with 1,4-dioxane using a time-domain reflectometry","year":2024,"lang":"en","type":"article","venue":"Canadian Journal of Physics","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Reflectometry; Dielectric; Permittivity; Intermolecular force; Hydrogen bond; Dielectric spectroscopy; Time domain; Relative permittivity; Relaxation (psychology); Physics; Solvent; Dielectric permittivity; Thermodynamics; Analytical Chemistry (journal); Molecule; Organic chemistry; Chemistry; Quantum mechanics; Electrode","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004208547,0.0004208285,0.0002812406,0.0002490976,0.0002214324,0.0001840367,0.0002109587,0.0001712639,0.0009881406],"category_scores_gemma":[0.0004358607,0.0002059175,0.0001894132,0.0004643846,0.00020747,0.0002933258,0.0001973524,0.000456035,0.0001578445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001666539,"about_ca_system_score_gemma":0.0001254021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001230187,"about_ca_topic_score_gemma":0.001057961,"domain_scores_codex":[0.9998222,0.00004316377,0.000008916391,0.00002889037,0.00006496027,0.00003192775],"domain_scores_gemma":[0.9997453,0.00009645477,0.00007026804,0.00001172073,0.00004643557,0.0000296582],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008979685,0.00002502263,0.0004268508,0.00005290729,0.00001047775,0.00006128322,0.00006622802,0.000333463,0.9975998,0.0000803383,0.00001465945,0.001239247],"study_design_scores_gemma":[0.000006890054,0.0002197882,0.006450464,0.000007046414,0.00001695895,0.0001509437,0.0001034235,0.003783061,0.9886115,0.00003291773,0.0006055683,0.00001146407],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994058,0.000935533,0.004119821,0.00003080364,0.00001394225,0.00001336331,0.00009294738,0.0000178334,0.0007176254],"genre_scores_gemma":[0.9928243,0.001393748,0.004430994,0.00002285057,0.000008572137,0.00001629019,0.0001322405,0.00001127775,0.001159713],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001230187,"threshold_uncertainty_score":0.003305614,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01704196305438399,"score_gpt":0.2443993908188845,"score_spread":0.2273574277645005,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}