{"id":"W4394840492","doi":"10.1021/jacs.4c00376","title":"Reversible [4 + 1] Cycloaddition of Arenes by a “Naked” Acyclic Aluminyl Compound","year":2024,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Academy of Finland; Engineering and Physical Sciences Research Council; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Steric effects; Cycloaddition; Ligand (biochemistry); Stereochemistry; Medicinal chemistry; Organic chemistry; Receptor; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001216887,0.0003943024,0.0001172516,0.0002022895,0.0001640273,0.0003118529,0.0002872813,0.0001831523,0.004132551],"category_scores_gemma":[0.00009012617,0.000225474,0.0001252616,0.0001216678,0.0002440345,0.0002248151,0.0002354941,0.0004451887,0.000859393],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002857628,"about_ca_system_score_gemma":0.0001712768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004972355,"about_ca_topic_score_gemma":0.001207691,"domain_scores_codex":[0.9998802,0.00001125239,0.000005119905,0.00004389881,0.00002555767,0.00003402676],"domain_scores_gemma":[0.9999367,0.00001378521,0.00001662459,0.00001628455,0.000005129676,0.0000115869],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006420405,0.00001085841,0.0000303494,0.00002878,0.000002246239,0.00004477721,0.00001715837,0.00009210103,0.9979232,0.0003183016,0.000126042,0.001341927],"study_design_scores_gemma":[0.00000685632,0.00009253842,0.0002800547,0.000001874312,0.000002117392,0.00005037772,0.000006551499,0.0002697223,0.9968951,0.00002649307,0.002364227,0.000004065343],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9664906,0.0006808763,0.01082445,0.0001471323,0.00008920777,0.00006420702,0.0005510427,0.0005967994,0.02055563],"genre_scores_gemma":[0.9779103,0.0004195605,0.008724506,0.00005120109,0.00001956337,0.00004818,0.0004326341,0.00009211882,0.01230178],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004132551,"threshold_uncertainty_score":0.0138247,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007568678477994911,"score_gpt":0.2409814454564887,"score_spread":0.2334127669784938,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}