{"id":"W4395680711","doi":"10.1039/d4sc00926f","title":"Mild and catalytic electrocyclizations of heptatrienyl anions","year":2024,"lang":"en","type":"article","venue":"Chemical Science","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Alliance de recherche numérique du Canada; York University; Université Grenoble Alpes","keywords":"Catalysis; Chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001693478,0.0003233033,0.0001411811,0.0001124944,0.0001910854,0.000208259,0.0001907662,0.0002393108,0.002139454],"category_scores_gemma":[0.0001950827,0.0001194606,0.0001510955,0.0001096253,0.0002543966,0.0003661432,0.0002626532,0.0006591844,0.0004332722],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001335365,"about_ca_system_score_gemma":0.0002473392,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002129075,"about_ca_topic_score_gemma":0.0006971121,"domain_scores_codex":[0.9998673,0.00001371065,0.00001264685,0.00003714197,0.00003624077,0.00003296803],"domain_scores_gemma":[0.999931,0.00001277987,0.00002194149,0.000007931015,0.00001279047,0.00001358709],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003888781,0.00001220571,0.00007018577,0.00005165347,0.000004165265,0.00009262357,0.00005139981,0.0001133486,0.9961123,0.0007239851,0.00007135402,0.002657926],"study_design_scores_gemma":[0.000005795506,0.00008998227,0.0003024557,0.000003354719,0.000003315319,0.0001169414,0.00002301024,0.0001283582,0.9954235,0.00009952221,0.003797708,0.000006045109],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9716073,0.002235,0.01516551,0.0002615984,0.0002075121,0.0001044622,0.0003607332,0.00009985963,0.00995791],"genre_scores_gemma":[0.9829679,0.001779011,0.008658721,0.0001264957,0.00004186303,0.00006852554,0.0002670791,0.00005490211,0.006035502],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002139454,"threshold_uncertainty_score":0.007157147,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009036122175151587,"score_gpt":0.2495107843882044,"score_spread":0.2404746622130528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}