{"id":"W4396674238","doi":"10.1021/acs.organomet.4c00065","title":"Alkene-Coordinated Palladium(0) Cross-Coupling Precatalysts: Comparing Oxidative Addition and Catalytic Reactivity for Dimethyl Fumarate and Maleic Anhydride Stabilizing Ligands","year":2024,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; British Columbia Knowledge Development Fund; University of Victoria","keywords":"Chemistry; Palladium; Denticity; Maleic anhydride; Catalysis; Alkene; Oxidative addition; Borylation; Phosphine; Cyclooctadiene; Heck reaction; Combinatorial chemistry; Organic chemistry; Reactivity (psychology); Medicinal chemistry; Alkyl; Aryl; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","scholarly_communication"],"consensus_categories":[],"category_scores_codex":[0.0005863872,0.0004981468,0.0006175853,0.0002588143,0.0004919697,0.001037469,0.0002144604,0.0002658924,0.0001257956],"category_scores_gemma":[0.0005386515,0.0005260953,0.0001565001,0.0006013745,0.0004170878,0.001212901,0.0002590392,0.0005214789,0.00002401148],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004700636,"about_ca_system_score_gemma":0.0001451745,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001873977,"about_ca_topic_score_gemma":0.0001479968,"domain_scores_codex":[0.9974383,0.000001866769,0.0005977873,0.001110852,0.0002611772,0.000590088],"domain_scores_gemma":[0.9977831,0.0009901631,0.0002150255,0.0005716354,0.0001951237,0.0002450036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008892099,0.0001024891,0.005615232,0.001179125,0.0003517464,0.0000180254,0.0007707205,0.0002395909,0.9894165,0.0002267495,0.00003206242,0.001958793],"study_design_scores_gemma":[0.000995934,0.00004751179,0.003917352,0.0004046297,0.0004687837,0.0001334874,0.0004539378,0.06671644,0.9239361,0.0006902257,0.001492747,0.0007428813],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955581,0.001695024,0.0007806462,0.0001037733,0.0002386917,0.00035902,0.0005197785,0.0004610155,0.0002839513],"genre_scores_gemma":[0.9968949,0.0002461075,0.0001596077,0.00001244001,0.0002289529,0.0001228094,0.001225441,0.0001436119,0.0009661349],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06647684,"threshold_uncertainty_score":0.9999995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0230464673621519,"score_gpt":0.2922271932951748,"score_spread":0.2691807259330229,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}