{"id":"W4396678399","doi":"10.1016/j.chempr.2024.04.006","title":"Hard single-molecule magnet behavior and strong magnetic coupling in pyrazinyl radical-bridged lanthanide metallocenes","year":2024,"lang":"en","type":"article","venue":"Chem","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":47,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Montréal; University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Kvantum-instituutti, Oulun Yliopisto; Oulun Yliopisto; Stavros Niarchos Foundation; Canada Foundation for Innovation; Academy of Finland; China Scholarship Council","keywords":"Lanthanide; Magnet; Pyrazine; Chemistry; Molecule; Ferrocene; Inductive coupling; Single-molecule magnet; Nanotechnology; Materials science; Crystallography; Magnetization; Physical chemistry; Stereochemistry; Organic chemistry; Physics; Magnetic field; Electrochemistry; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001146001,0.0001834645,0.0002600585,0.0001522312,0.0003063491,0.0003930042,0.0003831712,0.0002781026,0.001736176],"category_scores_gemma":[0.0002475872,0.0001444187,0.00006034316,0.0001162443,0.0003754608,0.0002101418,0.0003523178,0.0005443559,0.0001619275],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002705426,"about_ca_system_score_gemma":0.00008921949,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004019707,"about_ca_topic_score_gemma":0.0008261981,"domain_scores_codex":[0.9999222,0.00001300859,0.000003628563,0.0000167135,0.00001929475,0.00002526297],"domain_scores_gemma":[0.9998996,0.00003226756,0.00002069104,0.00001597893,0.00000997927,0.00002135978],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002628624,0.00002311999,0.0001761466,0.00009150329,0.000009165399,0.0001170239,0.0001168429,0.00009323322,0.9970762,0.0006109753,0.0001912941,0.001231662],"study_design_scores_gemma":[0.00005593453,0.0003672417,0.002209999,0.000006234436,0.00001364322,0.0001214586,0.00009063982,0.001309615,0.9939528,0.0001901731,0.00167012,0.00001213358],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981989,0.0001671104,0.0003221706,0.00008104154,0.00001365028,0.000004704406,0.00002500993,0.00003258316,0.001154738],"genre_scores_gemma":[0.9990541,0.00006642427,0.0002007317,0.00001844972,0.000004579805,0.000004222745,0.00003276273,0.00001088802,0.0006077681],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001736176,"threshold_uncertainty_score":0.005808055,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03167942183464267,"score_gpt":0.2688954943560882,"score_spread":0.2372160725214455,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}