{"id":"W4396690631","doi":"10.15278/isms.2023.6921","title":"ROTATIONAL AND INFRARED SPECTRA OF PYRIMIDINE: VIBRATIONAL GROUND STATE AND NINE VIBRATIONALLY EXCITED STATES","year":2023,"lang":"en","type":"article","venue":"","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Excited state; Ground state; Spectral line; Atomic physics; Infrared; Chemistry; Molecule; Physics; Optics; Quantum mechanics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006240257,0.0001284981,0.0001381632,0.00008236596,0.00008186913,0.00005777354,0.00005895001,0.00005679589,0.003252562],"category_scores_gemma":[0.00003861415,0.0001190467,0.00002543554,0.0001772869,0.0001067747,0.0001618076,0.00004369296,0.0000936033,0.0000048518],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001169621,"about_ca_system_score_gemma":0.00005850881,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000170467,"about_ca_topic_score_gemma":0.00002126117,"domain_scores_codex":[0.9991164,0.00001116929,0.0002431261,0.0002219132,0.000261794,0.0001455549],"domain_scores_gemma":[0.9995762,0.0001043633,0.00007703299,0.0001000121,0.00007273332,0.00006970698],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001202264,0.00002520193,0.005479537,0.000148417,0.0001131038,0.00001729726,0.0004710599,0.0009043906,0.9384599,0.05221204,0.001729772,0.0003189854],"study_design_scores_gemma":[0.001851454,0.0001003358,0.2068129,0.00004248467,0.00003347993,0.00005556867,0.0003578819,0.0545083,0.5361082,0.1988554,0.0007955807,0.0004784671],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9838869,0.0001040829,0.005349141,0.0005374918,0.00002363397,0.00006496818,0.0001839591,0.00006865089,0.009781187],"genre_scores_gemma":[0.9815032,0.000221566,0.009121579,0.0001900518,0.00009124457,0.00001769852,0.001337564,0.00002592895,0.007491098],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4023518,"threshold_uncertainty_score":0.9976586,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006160710584309947,"score_gpt":0.2292059732858078,"score_spread":0.2230452627014979,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}