{"id":"W4396692807","doi":"10.1039/d4ob00200h","title":"Stability and reactivity of alkylidene dihydropyridines","year":2024,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada; F. Hoffmann-La Roche","keywords":"Reactivity (psychology); Chemistry; Stability (learning theory); Mathematics; Computer science; Medicine","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001757804,0.0002066429,0.0002842508,0.00003137441,0.00004166338,0.00007506825,0.0001697599,0.0001742552,0.001641874],"category_scores_gemma":[0.0003596324,0.0001924856,0.0001513359,0.0004450695,0.0001470486,0.0001131642,0.0001476892,0.0001474078,0.00001025352],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000667984,"about_ca_system_score_gemma":0.00007387491,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005781661,"about_ca_topic_score_gemma":0.000001270776,"domain_scores_codex":[0.9987399,0.00001163383,0.0002742842,0.0005067061,0.0002614027,0.0002060463],"domain_scores_gemma":[0.9990454,0.0001593812,0.00007449272,0.000563589,0.00005281084,0.0001042798],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008155464,0.0000671341,0.000771963,0.0007710464,0.0001271542,0.00003898111,0.00004355314,7.943616e-9,0.9871456,0.00001002062,0.00006141727,0.01095498],"study_design_scores_gemma":[0.00008828158,0.000003980834,0.00009751969,0.00008398121,0.0001377357,0.00004802212,0.0000983078,0.0001383874,0.9967793,0.00005711865,0.002270214,0.000197159],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9816979,0.004837038,0.004381679,0.0001260432,0.00003292685,0.00003114521,0.00007230181,0.0001401472,0.008680782],"genre_scores_gemma":[0.9991451,0.0001997309,0.00009001681,0.000007866121,0.00006986866,0.000005366938,0.00003881129,0.00003804652,0.0004052127],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01744714,"threshold_uncertainty_score":0.9992707,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007120787032547383,"score_gpt":0.2119724602104202,"score_spread":0.2048516731778728,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}