{"id":"W4396869942","doi":"10.1007/s10973-024-13035-5","title":"Enthalpies of mixing for alloys liquid below room temperature determined by oxidative solution calorimetry","year":2024,"lang":"en","type":"article","venue":"Journal of Thermal Analysis and Calorimetry","topic":"Chemical Thermodynamics and Molecular Structure","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Polytechnique Montréal","funders":"Basic Energy Sciences","keywords":"Calorimetry; Mixing (physics); Thermodynamics; Differential scanning calorimetry; Materials science; Oxidative phosphorylation; Enthalpy; Entropy of mixing; Reaction calorimeter; Chemistry; Chemical engineering; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002579485,0.0002347675,0.0006218627,0.0002439415,0.00007550588,0.00007762115,0.0002167904,0.0002440141,0.0001227285],"category_scores_gemma":[0.00008710346,0.0001745184,0.000812875,0.0004954404,0.00006643394,0.0001305119,0.00006266003,0.0003739185,2.709634e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007134913,"about_ca_system_score_gemma":0.00004718964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003453424,"about_ca_topic_score_gemma":0.000004300357,"domain_scores_codex":[0.9985988,0.00002729675,0.0005802166,0.0002517649,0.0003197719,0.0002221115],"domain_scores_gemma":[0.9989982,0.0001564602,0.0003311526,0.0001744767,0.0002040829,0.0001356649],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000297172,0.00005057678,0.0002765376,0.0002033288,0.00304462,0.00001719563,0.0001345975,0.00004664966,0.9924499,0.0000658816,0.0002095006,0.003204024],"study_design_scores_gemma":[0.0004722776,0.0001573468,0.000168232,0.0001412015,0.002546217,0.00002552842,0.0001490877,0.004044262,0.9906866,0.0002494403,0.001118579,0.0002412382],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851621,0.009599554,0.004601764,0.0001142914,0.0001435672,0.00003916764,0.0001678559,0.00001247981,0.0001592115],"genre_scores_gemma":[0.9981601,0.00020196,0.0009483338,0.00003582659,0.0003133607,0.000002179507,0.00006150765,0.00002701585,0.0002496669],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01299804,"threshold_uncertainty_score":0.7116654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004854283693216511,"score_gpt":0.234809988598231,"score_spread":0.2299557049050145,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}