{"id":"W4396909560","doi":"10.1039/d4sc01524j","title":"Enhancing corannulene chemiluminescence, electrochemiluminescence and photoluminescence by means of an azabora-helicene to slow down its bowl inversion","year":2024,"lang":"en","type":"article","venue":"Chemical Science","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"National Key Research and Development Program of China; China Scholarship Council; Tianjin University; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Helicene; Corannulene; Electrochemiluminescence; Luminescence; Molecule; Chemiluminescence; Photoluminescence; Inversion (geology); Photochemistry; Chemistry; Boron; Luminescent Measurements; Nanotechnology; Materials science; Optoelectronics; Organic chemistry; Electrode; Physical chemistry; Geology; Paleontology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002275982,0.000341155,0.0002113769,0.0001300873,0.0001263303,0.0002831905,0.0002021113,0.0003185221,0.0009758878],"category_scores_gemma":[0.0001924125,0.0001223217,0.0001463796,0.0001072963,0.0003183696,0.0002481889,0.0002219285,0.0003292861,0.0002031219],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002219374,"about_ca_system_score_gemma":0.0001733797,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002872498,"about_ca_topic_score_gemma":0.0005318515,"domain_scores_codex":[0.9998734,0.00002555715,0.000007679783,0.00002868865,0.00002857906,0.0000360775],"domain_scores_gemma":[0.9998872,0.00002940899,0.00002935233,0.00001406756,0.00001766079,0.0000223026],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003515061,0.00000694627,0.00003959295,0.00003497562,0.000001992145,0.0000268559,0.0000190198,0.00002457412,0.9988186,0.0002476309,0.00001304688,0.000731597],"study_design_scores_gemma":[0.00000454956,0.00005974399,0.0001151334,0.000001120411,0.000002141227,0.00004229669,0.000004901813,0.0001070409,0.9989783,0.00001270961,0.0006695966,0.000002524727],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917216,0.00104155,0.004195278,0.0001074286,0.00002833639,0.0000300859,0.00006652098,0.00008944379,0.002719648],"genre_scores_gemma":[0.9947023,0.0003809831,0.003121621,0.0000354342,0.00000649043,0.00001802241,0.00005940969,0.00001442103,0.001661216],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009758878,"threshold_uncertainty_score":0.003264606,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006110839246370656,"score_gpt":0.2434554039817888,"score_spread":0.2373445647354182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}