{"id":"W4396945857","doi":"10.1039/d4tb00113c","title":"One-step synthesis of amphiphilic copolymers PDMS-<i>b</i>-PEG using tris(pentafluorophenyl)borane and subsequent study of encapsulation and release of curcumin","year":2024,"lang":"en","type":"article","venue":"Journal of Materials Chemistry B","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Universidad de Guanajuato","keywords":"Borane; Amphiphile; Copolymer; Encapsulation (networking); PEG ratio; Materials science; Curcumin; Tris; Polymer chemistry; Chemical engineering; Organic chemistry; Chemistry; Polymer; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003020624,0.000193776,0.0006888867,0.00007115248,0.00003212197,0.00003293846,0.0001263909,0.0001214555,0.0004016554],"category_scores_gemma":[0.000138183,0.0001856736,0.00007591637,0.0001077277,0.0001178017,0.0002042265,0.00004909953,0.00009335892,1.058745e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004735195,"about_ca_system_score_gemma":0.0000699344,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005098113,"about_ca_topic_score_gemma":3.787557e-7,"domain_scores_codex":[0.9980248,0.00005613226,0.001232634,0.0002009185,0.0003504145,0.0001351086],"domain_scores_gemma":[0.9981942,0.0001715351,0.001208762,0.0002048257,0.0001319134,0.00008882173],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003973863,0.0003025933,0.0004853535,0.002617969,0.0001917028,0.00001343848,0.0004404336,0.00002048437,0.9923928,0.000004419177,0.000002261081,0.003131102],"study_design_scores_gemma":[0.0005933694,0.00006330443,0.0003486912,0.001238059,0.0004200434,0.00006868782,0.000933207,0.00008403696,0.996064,0.00002626338,0.00001793637,0.0001424003],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974254,0.00211184,0.00008347558,0.0000267459,0.00009925303,0.00007297061,0.0001292778,0.000008024186,0.00004299541],"genre_scores_gemma":[0.9991115,0.0004488655,0.0002214169,0.00000204976,0.0001564574,0.000003311407,0.000008089173,0.00003057695,0.00001777227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003671144,"threshold_uncertainty_score":0.757155,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01686146989493635,"score_gpt":0.2532950712946389,"score_spread":0.2364336013997026,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}