{"id":"W4397023410","doi":"10.1021/acssuschemeng.4c02486","title":"A Sustainable Access Route to Carbazoles via C–H/C–H Oxidative Functionalization/Cyclization of Arylamines","year":2024,"lang":"en","type":"article","venue":"ACS Sustainable Chemistry & Engineering","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Canada Research Chairs; Natural Sciences and Engineering Research Council of Canada; European Commission; China Scholarship Council; Canada Foundation for Innovation; Istituto Nazionale Previdenza Sociale","keywords":"Carbazole; Intramolecular force; Oxidative coupling of methane; Combinatorial chemistry; Chemistry; Catalysis; Surface modification; Molecule; Molecular oxygen; Oxidative phosphorylation; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001457939,0.0005486981,0.0001813477,0.0002693856,0.000253288,0.0002128226,0.0004923905,0.0003932427,0.001731114],"category_scores_gemma":[0.0001145479,0.0001754643,0.0002809793,0.0002208418,0.0002467682,0.0003909495,0.0003921661,0.0006793474,0.000490249],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003171282,"about_ca_system_score_gemma":0.0004898632,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001363762,"about_ca_topic_score_gemma":0.003462004,"domain_scores_codex":[0.9998537,0.00001123768,0.00001454564,0.00003889338,0.00003488878,0.00004666645],"domain_scores_gemma":[0.9999592,0.000005028251,0.00001181484,0.000007254464,0.000006643244,0.00001005773],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006993742,0.000140919,0.0002117289,0.0003680366,0.00002939883,0.0005825112,0.0001228626,0.0005363403,0.9734403,0.002757266,0.0009761244,0.0207646],"study_design_scores_gemma":[0.00004801999,0.0006864853,0.001376285,0.00001821393,0.00003229027,0.0006650983,0.00003997123,0.001682967,0.9766473,0.0003283815,0.01844084,0.00003435544],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8823491,0.01526113,0.0681546,0.0007533127,0.000283668,0.0003978974,0.001164648,0.001030381,0.03060521],"genre_scores_gemma":[0.9839932,0.003523744,0.008533485,0.0001307769,0.00003041415,0.00006535643,0.0003088299,0.00003122533,0.003383107],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001731114,"threshold_uncertainty_score":0.005791187,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009215581639973007,"score_gpt":0.2599173489004236,"score_spread":0.2507017672604506,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}