{"id":"W4398161919","doi":"10.1021/acsomega.3c09975","title":"Oxidative and Extractive Desulfurization of Fuel Oils Catalyzed by <i>N</i>-Carboxymethyl Pyridinium Acetate and <i>N</i>-Carboxyethyl Pyridinium Acetate Acidic Ionic Liquids: Experimental and Computational DFT Study","year":2024,"lang":"en","type":"article","venue":"ACS Omega","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Ministry of Education – Kingdom of Saudi Arabi","keywords":"Pyridinium; Flue-gas desulfurization; Chemistry; Ionic liquid; Ionic bonding; Catalysis; Oxidative phosphorylation; Organic chemistry; Inorganic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001307811,0.0004123444,0.0003196534,0.0002332339,0.000134243,0.0001839717,0.0005520236,0.0002642429,0.00150912],"category_scores_gemma":[0.000157623,0.0001596656,0.0003248425,0.0002572371,0.0001920313,0.0003655649,0.0002090997,0.0002209596,0.000143136],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003872285,"about_ca_system_score_gemma":0.0002128589,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003092607,"about_ca_topic_score_gemma":0.003403298,"domain_scores_codex":[0.9999621,0.000003803992,0.000002218497,0.000006106954,0.00001430323,0.00001144491],"domain_scores_gemma":[0.9999547,0.00001883735,0.00001045041,0.000003832954,0.000008124437,0.00000403268],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008734146,0.0002591587,0.004755437,0.001394289,0.00009693997,0.0008980102,0.0001908209,0.3333569,0.6221899,0.009708494,0.000824446,0.0254521],"study_design_scores_gemma":[0.00007007716,0.0002619197,0.002322585,0.00001426716,0.00004002881,0.00006566924,0.00008107013,0.7143384,0.2806897,0.0005083766,0.00158283,0.00002504588],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922179,0.0003989378,0.003453283,0.0000446702,0.000006505053,0.00001362872,0.0003100593,0.00004696829,0.003507997],"genre_scores_gemma":[0.9959442,0.0004384259,0.002631373,0.000008677103,0.000002709806,0.00002004616,0.0002216419,0.000008467016,0.0007244507],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003092607,"threshold_uncertainty_score":0.006149232,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01274843092668929,"score_gpt":0.2582125562212235,"score_spread":0.2454641252945342,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}