{"id":"W4398766905","doi":"10.1002/chem.202401559","title":"Porphyrin Atropisomerism as a Molecular Engineering Tool in Medicinal Chemistry, Molecular Recognition, Supramolecular Assembly, and Catalysis","year":2024,"lang":"en","type":"review","venue":"Chemistry - A European Journal","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"HORIZON EUROPE Marie Sklodowska-Curie Actions; Irish Research Council; Science Foundation Ireland","keywords":"Atropisomer; Supramolecular chemistry; Porphyrin; Molecular recognition; Chemistry; Catalysis; Supramolecular catalysis; Combinatorial chemistry; Nanotechnology; Stereochemistry; Materials science; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004679438,0.0007422436,0.0007516555,0.00193744,0.0002974322,0.0006950062,0.0005252115,0.0007843442,0.002093527],"category_scores_gemma":[0.0003231831,0.0004111845,0.0003097068,0.002279196,0.0004263485,0.001167003,0.0006580919,0.001488046,0.001926978],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000616598,"about_ca_system_score_gemma":0.0007522219,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006845793,"about_ca_topic_score_gemma":0.001131397,"domain_scores_codex":[0.9998505,0.00002126448,0.0000141077,0.00003095579,0.00006040934,0.00002270885],"domain_scores_gemma":[0.9998982,0.00003471238,0.00001680471,0.000005337813,0.00002925022,0.00001571809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00007214624,0.0001517913,0.0001418882,0.01457126,0.00006121034,0.0003485023,0.000120636,0.0009125561,0.01419972,0.01544476,0.01845207,0.9355235],"study_design_scores_gemma":[0.00001326721,0.0001254579,0.0005447441,0.001201231,0.00004136227,0.0008966664,0.00004176224,0.0001645708,0.002845809,0.002074862,0.9920307,0.00001963049],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0006913773,0.9961021,0.0004175036,0.0002407806,0.0001918044,0.000009566176,0.00001722688,0.00001509438,0.002314451],"genre_scores_gemma":[0.003543987,0.9940029,0.0004928595,0.0001750196,0.0001426262,0.00001753233,0.00003012972,0.000002683403,0.001592231],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.002093527,"threshold_uncertainty_score":0.007003546,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01569285990218161,"score_gpt":0.2626913435123557,"score_spread":0.2469984836101741,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}