{"id":"W4399086754","doi":"10.1016/j.jnoncrysol.2024.123044","title":"Valence band XPS spectra of K silicate glasses: Effect of HOMO energies on K, Na and Li leach rates, activation energies and reaction mechanism","year":2024,"lang":"en","type":"article","venue":"Journal of Non-Crystalline Solids","topic":"Glass properties and applications","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto; Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"X-ray photoelectron spectroscopy; Silicate; Valence (chemistry); Spectral line; Activation energy; Valence band; Silicate glass; Materials science; Chemistry; Analytical Chemistry (journal); Physical chemistry; Mineralogy; Physics; Nuclear magnetic resonance; Band gap","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008317213,0.0002028448,0.00009712355,0.0002075987,0.000189306,0.0001466894,0.0001370753,0.000249076,0.003036743],"category_scores_gemma":[0.0001345118,0.0001045005,0.0002039327,0.0001530969,0.0001833078,0.0001817348,0.0001193164,0.0001635408,0.0002924873],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001431095,"about_ca_system_score_gemma":0.000159489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002538613,"about_ca_topic_score_gemma":0.002964899,"domain_scores_codex":[0.9999474,0.000003295035,0.000004319712,0.00001259709,0.00001541513,0.00001698824],"domain_scores_gemma":[0.999941,0.0000217524,0.000007333084,0.000004103707,0.00001857518,0.000007147873],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004576014,0.0000166647,0.00208257,0.00005613485,0.000009446691,0.00004799636,0.00008350231,0.0003609754,0.9928827,0.0001257949,0.0001181152,0.003758413],"study_design_scores_gemma":[0.000005348577,0.0001750544,0.02032495,0.000006043861,0.0000169567,0.0001077707,0.0002542946,0.002188609,0.9758468,0.0001391016,0.0009221809,0.00001297019],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973351,0.0001492185,0.001017946,0.00002615376,0.000008709223,0.00000332322,0.0003980519,0.00003491888,0.001026532],"genre_scores_gemma":[0.9983103,0.00008480802,0.000268424,0.00001533628,0.000001371232,0.000002200394,0.0002955273,0.000008172121,0.001013727],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003036743,"threshold_uncertainty_score":0.0101589,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009288596700100833,"score_gpt":0.2629699342318199,"score_spread":0.253681337531719,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}