{"id":"W4399391929","doi":"10.3762/bxiv.2024.37.v1","title":"Synthesis and Conformational Analysis of Pyran Inter-Halide Analogues of D-Talose","year":2024,"lang":"en","type":"preprint","venue":"","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Pyran; Halide; Chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005125784,0.0001303459,0.0001010652,0.00008138169,0.00008410031,0.0001855506,0.0001782516,0.00007952037,0.000912648],"category_scores_gemma":[0.0001128447,0.0000500488,0.0001226784,0.0001515515,0.00008932754,0.0001285991,0.0001350781,0.0002929782,0.0001684782],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001435009,"about_ca_system_score_gemma":0.00009359913,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003125434,"about_ca_topic_score_gemma":0.0003963533,"domain_scores_codex":[0.9999659,0.000006631167,0.000002597119,0.000007299886,0.000008335277,0.000009142863],"domain_scores_gemma":[0.9999591,0.000006355807,0.00001032409,0.000008469186,0.000006844866,0.000008909162],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001603643,0.00003134744,0.0002756483,0.00008202765,0.00001075437,0.0001848929,0.00006374285,0.002033598,0.9909987,0.0005329876,0.00004414623,0.005581778],"study_design_scores_gemma":[0.00001253235,0.0003875547,0.0009248189,0.000003429069,0.0000115306,0.0001604174,0.00002874758,0.001328607,0.9941708,0.0001340376,0.002828756,0.000008792676],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953758,0.0003780003,0.002380747,0.00002940608,0.000009738856,0.00001213281,0.0001385775,0.00001581448,0.001659759],"genre_scores_gemma":[0.9956085,0.0003616525,0.002787716,0.00002889706,0.00000301608,0.00001010989,0.0002734404,0.00001031057,0.0009163773],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000912648,"threshold_uncertainty_score":0.003053069,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01828696019023716,"score_gpt":0.2518988737545627,"score_spread":0.2336119135643255,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}