{"id":"W4399828199","doi":"10.32920/26052769","title":"Synthesis of Organosilanes and Investigation of Their Catalytic Activity for Direct Amide Bond Formation","year":2024,"lang":"en","type":"preprint","venue":"","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University","funders":"","keywords":"Amide; Catalysis; Chemistry; Bond; Peptide bond; Polymer chemistry; Organic chemistry; Business","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001548518,0.0002685604,0.0001744482,0.0002692773,0.000105411,0.0002433734,0.0001694786,0.0002864212,0.001435183],"category_scores_gemma":[0.0002098209,0.0001275999,0.0002583023,0.0002375893,0.00008721427,0.0002621521,0.0000979888,0.0003469551,0.0003789208],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001895623,"about_ca_system_score_gemma":0.0001557472,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002536652,"about_ca_topic_score_gemma":0.0005965229,"domain_scores_codex":[0.9998975,0.000008073507,0.00001027922,0.0000218458,0.00004151546,0.00002087206],"domain_scores_gemma":[0.9998955,0.00002439041,0.00003304217,0.000007090897,0.00002682531,0.0000132764],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002355811,0.00002354549,0.00009843626,0.0001913611,0.000007329229,0.00007556316,0.0000195945,0.0001473167,0.9963881,0.000139943,0.00006004173,0.002825259],"study_design_scores_gemma":[0.000004321696,0.0002026331,0.0005220232,0.00001628469,0.000008894071,0.00009221814,0.00001803193,0.0002266796,0.9957723,0.00002215664,0.003110548,0.000003942981],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9769768,0.01029993,0.003948424,0.0001122779,0.00004812084,0.00006799833,0.000540829,0.00007576697,0.007929833],"genre_scores_gemma":[0.9778358,0.008408715,0.008584188,0.00005650806,0.0000155398,0.00005989755,0.0007449236,0.00002988477,0.004264639],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001435183,"threshold_uncertainty_score":0.004801214,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01197815907620847,"score_gpt":0.2308592518809692,"score_spread":0.2188810928047608,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}