{"id":"W4399860902","doi":"10.1038/s44160-024-00568-8","title":"Efficient ethylene electrosynthesis through C–O cleavage promoted by water dissociation","year":2024,"lang":"en","type":"article","venue":"Nature Synthesis","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":67,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Catalysis; Selectivity; Dissociation (chemistry); Electrosynthesis; Chemistry; Ethylene; Electrochemistry; Ethylene carbonate; Inorganic chemistry; Photochemistry; Adsorption; Hydrogen; Faraday efficiency; Electrode; Organic chemistry; Electrolyte; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003546424,0.0002708313,0.0002712588,0.0001269523,0.0001682639,0.0001379549,0.0002243703,0.0006409903,0.0008105981],"category_scores_gemma":[0.0001979084,0.0001932098,0.0002526806,0.0004030769,0.0000433913,0.0001029571,0.00004989759,0.0006242889,0.0003035818],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002866482,"about_ca_system_score_gemma":0.00002702925,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001902025,"about_ca_topic_score_gemma":0.0000203929,"domain_scores_codex":[0.9981428,0.0001212998,0.0002859062,0.0005551104,0.0004323555,0.0004625324],"domain_scores_gemma":[0.9992608,0.0001916463,0.00004611178,0.0003769322,0.00006061287,0.00006388537],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005133649,0.0002057969,0.000005848654,0.000134929,0.0002628872,0.00002068199,0.0009274117,0.00004048643,0.7456594,0.008380891,0.05021116,0.1940992],"study_design_scores_gemma":[0.00003288475,0.00002086943,0.00002554837,0.00007190584,0.00008856449,0.00000933544,0.00004124653,0.0004352975,0.7838054,0.001169231,0.214072,0.000227682],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8136653,0.02347714,0.005487323,0.02966275,0.003299544,0.001666755,0.0003647031,0.008712611,0.1136639],"genre_scores_gemma":[0.9961289,0.0001552244,0.0003842165,0.0001363092,0.0002782742,0.0001452529,0.00007190245,0.00008116654,0.002618711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1938716,"threshold_uncertainty_score":0.887548,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004126896536308712,"score_gpt":0.2426252015725191,"score_spread":0.2384983050362104,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}