{"id":"W4399957756","doi":"10.1021/acs.iecr.4c01811","title":"Scalable Routes to Acrylate and Methacrylate Block Copolymers via Copper-Mediated Reversible Deactivation Radical Polymerization","year":2024,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Copolymer; Acrylate; Methacrylate; Copper; Polymer chemistry; Polymerization; Radical polymerization; Block (permutation group theory); Chemistry; Chemical engineering; Materials science; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004638883,0.0002976517,0.0003032389,0.0001930595,0.0001836942,0.0002588285,0.000249351,0.0004924258,0.0005353391],"category_scores_gemma":[0.0006997961,0.0003208631,0.00006385089,0.001047157,0.00009384701,0.0003309404,0.0001565526,0.0009594387,0.00004338605],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002668737,"about_ca_system_score_gemma":0.0001718325,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007404902,"about_ca_topic_score_gemma":4.032277e-7,"domain_scores_codex":[0.9975818,0.00003404418,0.0004115645,0.0006359674,0.0006524259,0.0006841883],"domain_scores_gemma":[0.9985839,0.0005484257,0.00005093418,0.0003188133,0.00009520449,0.000402753],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007651273,0.00002851252,0.0001345245,0.0002211675,0.00007693039,0.00001934548,0.0001191982,0.0004209561,0.9887309,0.00001635322,0.0004779117,0.009677701],"study_design_scores_gemma":[0.0003842613,0.00001994005,0.00001733149,0.0004167471,0.00002343548,0.00002274505,0.00006890752,0.01284538,0.9660993,0.000007625735,0.01977771,0.0003166093],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950665,0.001107765,0.0004709823,0.001166864,0.000295059,0.0002181113,0.0001071115,0.000470236,0.001097345],"genre_scores_gemma":[0.9960127,0.000123661,0.00007302257,0.00001852415,0.0009487946,0.0000725443,0.0002019109,0.00009404257,0.002454805],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02263158,"threshold_uncertainty_score":0.9999244,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03692808942614446,"score_gpt":0.297765834388536,"score_spread":0.2608377449623915,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}