{"id":"W4399993798","doi":"10.1139/cjc-2024-0101","title":"A purification-free method for the synthesis of thiazolium salts using P <sub>2</sub> S <sub>5</sub> -Py <sub>2</sub> complex or P <sub>4</sub> S <sub>10</sub>","year":2024,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Quinazolinone synthesis and applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Alliance de recherche numérique du Canada; Western Canada Research Grid","keywords":"Chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.002549532,0.001745636,0.002304448,0.0007173285,0.001525217,0.000850158,0.003511006,0.001440468,0.000315835],"category_scores_gemma":[0.003228416,0.001614877,0.001932527,0.001817184,0.001052119,0.0006674588,0.0003190356,0.002259576,0.0000882563],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001754754,"about_ca_system_score_gemma":0.00756056,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002882289,"about_ca_topic_score_gemma":0.001745833,"domain_scores_codex":[0.9901597,0.0002768078,0.003626695,0.001879375,0.001558809,0.002498623],"domain_scores_gemma":[0.9860746,0.00411674,0.002478305,0.003253161,0.001755382,0.002321831],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002800621,0.0002588634,0.00005306629,0.00218023,0.001148061,0.0001700034,0.0004352125,0.0004916467,0.9110917,0.0001991365,0.02172882,0.06196324],"study_design_scores_gemma":[0.001344641,0.00006220964,0.0002194335,0.002194288,0.001751013,0.0009963425,0.001114844,0.003952289,0.9783014,0.001303577,0.007176057,0.001583872],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9792256,0.003627905,0.005615664,0.004632313,0.0006028986,0.000996753,0.003074756,0.0002160514,0.002008097],"genre_scores_gemma":[0.9921678,0.001221128,0.002198291,0.0004574583,0.002663252,0.000496903,0.0002181201,0.000477509,0.00009954915],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06720977,"threshold_uncertainty_score":0.9998559,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03167374223613795,"score_gpt":0.2697794885162836,"score_spread":0.2381057462801457,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}