{"id":"W4399993798","doi":"10.1139/cjc-2024-0101","title":"A purification-free method for the synthesis of thiazolium salts using P <sub>2</sub> S <sub>5</sub> -Py <sub>2</sub> complex or P <sub>4</sub> S <sub>10</sub>","year":2024,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Quinazolinone synthesis and applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Alliance de recherche numérique du Canada; Western Canada Research Grid","keywords":"Chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002558586,0.0007208157,0.000405395,0.0004577137,0.0003942245,0.000324237,0.0007106957,0.0005312298,0.003986384],"category_scores_gemma":[0.000377377,0.0003600193,0.0003487728,0.00044524,0.0003228668,0.0004241798,0.0004856763,0.001334625,0.002489709],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003152701,"about_ca_system_score_gemma":0.0008806768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001001242,"about_ca_topic_score_gemma":0.002285391,"domain_scores_codex":[0.9997767,0.00002820134,0.00002069102,0.00004809971,0.0000969561,0.00002929003],"domain_scores_gemma":[0.9998017,0.00004446088,0.00004703885,0.00004444617,0.00004485098,0.00001756807],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004553311,0.00004879384,0.0001334563,0.0002777781,0.00002468501,0.0002332446,0.0000751925,0.0002206955,0.9796371,0.0008873139,0.0007146187,0.01770155],"study_design_scores_gemma":[0.00002033777,0.0002508276,0.0006502336,0.00001331366,0.00003211775,0.000922774,0.00002735371,0.0008099657,0.9830706,0.0002495366,0.01392278,0.00003011032],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.2853801,0.01037388,0.6750057,0.0007770419,0.0003615693,0.001118404,0.001615287,0.003162751,0.02220525],"genre_scores_gemma":[0.7325534,0.009653999,0.2349378,0.0002725009,0.00005705707,0.0006391677,0.001663259,0.0003079077,0.01991485],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.003986384,"threshold_uncertainty_score":0.01333582,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03167374223613795,"score_gpt":0.2697794885162836,"score_spread":0.2381057462801457,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}